The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[20] This is in accordance with the generally-accepted representation
of the relations between salts and the hydrates of acids, but it
is of little help in the study of siliceous compounds. Generally
speaking, it becomes necessary to explain the property of
(SiO_{2})_{_n_} to combine with (RO)_{_m_}, where _n_ may be
greater than _m_, and where R may be H_{2}, Ca, &c. Here we are
aided by those facts which have been attained by the investigation
of carbon compounds, especially with respect to glycol. Glycol is
a compound having the composition C_{2}H_{6}O_{2}, only differing
from alcohol, C_{2}H_{6}O, by an extra atom of oxygen. This
hydrate contains two hydroxyl groups, which may be successively
replaced by chlorine, &c. Hence the composition of glycol should
be represented as C_{2}H_{4}(OH)_{2}. It has been found that
glycol forms so-called polyglycols. Their origin will be
understood from the fact that glycol as a hydrate has a
corresponding anhydride of the composition C_{2}H_{4}O, known as
ethylene oxide. This substance is ethane, C_{2}H_{6}, in which two
hydrogens are replaced by one atom of oxygen. Ethylene oxide is
not the only anhydride of glycol, although it is the simplest one,
because C_{2}H_{4}O = C_{2}H_{4}(OH)_{2} - H_{2}O. Various other
anhydrides of glycol are possible, and have actually been
obtained, of the composition _n_C_{2}H_{4}(OH)_{2} - (_n_ -
1)H_{2}O = (C_{2}H_{4})_{_n_}O_{_n_ - 1}(OH)_{2}. These imperfect
anhydrides of glycol, or _polyglycols_, still contain hydroxyls
like glycol itself, and therefore are of an alcoholic character in
the same sense as glycol itself. They are obtained by various
methods, and, amongst others, by the direct combination of
ethylene oxide with glycol, because C_{2}H_{4}(OH)_{2} + (_n_ -
1)C_{2}H_{4}O = (C_{2}H_{4})_{_n_}O_{_n_ - 1}(OH)_{2}. The most
important circumstance, from a theoretical point of view, is that
these polyglycols may be distilled without undergoing
decomposition, and that the general formula given above expresses
their actual molecular composition. Hence we have here a direct
combination of the anhydride with the hydrate, and, moreover, a
repeated one. The formula A_{_n_}H_{2}O may be used to express the
composition of glycol and polyglycols with respect to ethylene
oxide in the most simple manner, if A stand for ethylene oxide.
When _n_ = 1 we have glycol, when _n_ is greater than 1 a
polyglycol. Such also is the relationship of the salts of hydrate
of silica, if A stand for silica, and if we imagine that H_{2}O
may also be taken _m_ times. Such a representation of the
_polysilicic acids_ corresponds with the representation of the
polymerism of silica.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account