The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Laurent supposed the existence of several
polymeric forms, Si_{2}O_{4}, Si_{3}O_{6}, &c., besides silica,
SiO_{2}.
The formation of crystalline rocks in nature is partly of such a
nature. By aqueous or igneous agency, but in any case in a liquid
condition, those oxides which form the earth's crust and her crystalline
minerals came into mutual contact. First of all they formed a shapeless
mass, of which lava, glass, slags and solutions are examples, but little
by little, or else suddenly, some definite compounds of certain oxides
existing in this alloy or in the shapeless mass were formed. This is
entirely similar to two metals forming a homogeneous alloy,[21] and under
known circumstances (for instance, on cooling the alloy, or in the case
of aqueous solution when the two metals are simultaneously liberated from
the solution), definite crystalline compounds are separated. In any case
there is no doubt that there is less distinction between silica and
bases, than between bases and such anhydrides as, for instance, sulphuric
or nitric, or even carbonic, as is seen on comparing the physical and
chemical properties of silica and various kinds of oxides. Alumina,
especially, is exceedingly near akin to silica; not only in the hydrated
state, but also in the anhydrous condition, there exists a certain
similarity between the crystalline forms of alumina and silica, in the
uncombined state. Both are very hard, transparent, inactive,
non-volatile, infusible, and crystallise in the hexagonal system--in a
word, they are remarkably similar, and for this reason they are capable,
like two kindred metals, of entering into many different degrees of
combination. Isomorphous mixtures--that is, differing by the substitution
of oxides akin both in their physical and chemical characters--are very
frequently met with among minerals, and the study of the latter gave the
principal impetus to the study of isomorphism. Thus, in a whole series of
minerals, lime and magnesia are found in variable and interchangeable
proportions. Exactly the same may be said of potassium and sodium, of
alumina and ferric oxide, of manganous, ferrous, magnesium oxides, &c.
Such isomorphism does not, however, extend without change of form and
properties beyond certain rather narrow limits.[22] What I mean by this
is that lime is not always replaced totally, but often only in small
quantities, by magnesia, or by the manganous and ferrous oxides, without
changing the crystalline form. The same may be observed with regard to
potassium and lithium, which may be in part, but not completely, replaced
by sodium. On the total substitution of one metal for another, often
(although not invariably) the entire nature of the substance is changed;
for instance, _enstatite_ (or bronzite) is a magnesium bisilicate with a
small isomorphous substitution of calcium for magnesium; its composition
is expressed by the formula MgSiO_{3}, it belongs to the rhombic system.
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