The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
was enclosed in a steel tube and heated to dull redness. When the
mixture contained an excess of silica the residue contained many
crystals of rock crystal and tridymite, together with a powder of
felspar, which formed the main product of the reaction when the
proportion of hydrate of silica was decreased, and a mixture of a
solution of potassium silicate with alumina precipitated together
with the silica by mixing soluble glass with aluminium chloride
was employed. The composition, properties, and forms of the
resultant felspar proved it to be identical with that found in
nature. The experiments approach very nearly to the natural
conditions, all the more as felspar and quartz are obtained
together in one mixture, as they so often occur in nature.
Such complex silicates are generally insoluble in water,[25] and if
they undergo change in it, it is but very slow, and more often only in
the presence of carbonic acid. Some of the silicates which are insoluble
in water are easily and directly decomposed by acids; for instance, the
zeolites and those fused silicates which contain a large quantity of
energetic bases--such as lime. Many of the silicates, like glass,[26] are
hardly changed by acids, particularly if they contain much silica, whilst
fusion with alkalis leads to the formation of compounds rich in bases,
after which acids decompose the alloys formed.[27]
[25] The application of _cements_ is based on this principle; they are
those sorts of 'hydraulic' lime which generally form a stony mass,
which hardens even under water, when mixed with sand and water.
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