The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The hydraulic properties of cements are due to their containing
calcareous and silico-aluminous compounds which are able to
combine with water and form hydrates, which are then unacted on by
water. This is best proved, in the first place, by the fact that
certain slags containing lime and silica, and obtained by fusion
(for example, in blast-furnaces), solidify like cements when
finely ground and mixed with water; and, in the second place, by
the method now employed for the manufacture of artificial cements
(formerly only peculiar and comparatively rare natural products
were used). For this purpose a mixture of lime and clay is taken,
containing about 25 p.c. of the latter; this mixture is then
heated, not to fusion, but until both the carbonic anhydride and
water contained in the clay are expelled. This mass when finely
ground forms Portland cement, which hardens under water. The
process of hardening is based on the formation of chemical
compounds between the lime, silica, alumina, and water. These
substances are also found combined together in various natural
minerals--for example, in the zeolites, as we saw above. In all
cases cement which has set contains a considerable amount of
water, and its hardening is naturally due to hydration--that is,
to the formation of compounds with water. Well-prepared and very
finely-ground cement hardens comparatively quickly (in several
days, especially after being rammed down), with 3 parts (and even
more) of coarse sand and with water, into a stony mass which is as
hard and durable as many stones, and more so than bricks and
limestone. Hence not only all maritime constructions (docks,
ports, bridges, &c.), but also ordinary buildings, are made of
Portland cement, and are distinguished for their great durability.
A combination of ironwork (ties, girders) and cement is
particularly suitable for the construction of aqueducts, arches,
reservoirs, &c. Arches and walls made of such cements may be much
less thick than those built up of ordinary stone. Hence the
production and use of cement rapidly increases from year to year.
The origin of accurate data respecting cements is chiefly due to
Vicat. In Russia Professor Schuliachenko has greatly aided the
extension of accurate data concerning Portland cement. Many works
for the manufacture of cement have already been established in
various parts of Russia, and this industry promises a great future
in the arts of construction.
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