The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[26] _Glass_ presents a similar complex composition, like that of many
minerals. The ordinary sorts of white glass contain about 75 p.c.
of silica, 13 p.c. of sodium oxide, and 12 p.c of lime; but the
inferior sorts of glass sometimes contain up to 10 p.c. of
alumina. The mixtures which are used for the manufacture of glass
are also most varied. For example, about 300 parts of pure sand,
about 100 parts of sodium carbonate, and 50 of limestone are
taken, and sometimes double the proportion of the latter. Ordinary
_soda-glass_ contains sodium oxide, lime, and silica as the chief
component parts. It is generally prepared from sodium sulphate
mixed with charcoal, silica, and lime (Chapter XII.), in which
case the following reaction takes place at a high temperature:
Na_{2}SO_{4} + C + SiO_{2} = Na_{2}SiO_{3} + SO_{2} + CO.
Sometimes potassium carbonate is taken for the preparation of the
better qualities of glass. In this case a glass, _potash-glass_,
is obtained containing potassium oxide instead of sodium oxide.
The best-known of these glasses is the so-called Bohemian glass or
crystal, which is prepared by the fusion of 50 parts of potassium
carbonate, 15 parts of lime, and 100 parts of quartz. The
preceding kinds of glass contain lime, whilst crystal glass
contains lead oxide instead. Flint glass--that is, the lead glass
used for optical instruments--is prepared in this manner,
naturally from the purest possible materials.
_Crystal-glass_--_i.e._ glass containing lead oxide--is softer
than ordinary glass, more fusible and has a higher index of
refraction. However, although the materials for the preparation of
glass be most carefully sorted, a certain amount of iron oxides
falls into the glass and renders it greenish. This coloration may
be destroyed by adding a number of substances to the vitreous
mass, which are able to convert the ferrous oxide into ferric
oxide; for example, manganese peroxide (because the peroxide is
deoxidised to manganous oxide, which only gives a pale violet tint
to the glass) and arsenious anhydride, which is deoxidised to
arsenic, and this is volatilised. The manufacture of glass is
carried on in furnaces giving a very high temperature (often in
regenerative furnaces, Chapter IX.). Large clay crucibles are
placed in these furnaces, and the mixture destined for the
preparation of the glass, having been first roasted, is charged
into the crucibles. The temperature of the furnace is then
gradually raised. The process takes place in three separate
stages. At first the mass intermixes and begins to react; then it
fuses, evolves carbonic acid gas, and forms a molten mass; and,
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