The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[47] The normal lead acetate, known in trade as _sugar of lead_, owing
to its having a sweetish taste, has the formula
Pb(C_{2}H_{3}O_{2})_{2},3H_{2}O. This salt only crystallises from
acid solutions. It is capable of dissolving a further quantity of
lead oxide or of metallic lead in the presence of air. A basic
salt of the composition Pb(C_{2}H_{3}O_{2})_{2},PbH_{2}O_{2} is
then formed which is soluble in water and alcohol. As in this salt
the number of atoms is even and the same as in the hydrate of
acetic acid, C_{2}H_{4}O_{2},H_{2}O = C_{2}H_{3}(OH)_{3}, it may
be represented as this hydrate in which two of hydrogen are
replaced by lead--that is, as C_{2}H_{3}(OH)(O_{2}Pb). This basic
salt is used in medicine as a remedy for inflammation, for
bandaging wounds, &c., and also in the manufacture of white lead.
Other basic acetates of lead, containing a still greater amount of
lead oxide, are known. According to the above representation of
the composition of the preceding lead acetate, a basic salt of the
composition (C_{2}H_{3})_{2}(O_{2}Pb)_{3} would be also possible,
but what appear to be still more basic salts are known. As the
character of a salt also depends on the property of the base from
which it is formed, it would seem that lead forms a hydroxide of
the composition HOPbOH, containing two water residues, one or both
of which may be replaced by the acid residues. If both water
residues are replaced, a normal salt, XPbX, is obtained, whilst if
only one is replaced a basic salt, XPbOH, is formed. But lead does
not only give this normal hydroxide, but also polyhydroxides,
Pb(OH),_n_PbO, and if we may imagine that in these polyhydroxides
there is a substitution of both the water residues by acid
residues, then the power of lead for forming basic salts is
explained by the properties of the base which enters into their
composition.
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