The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[6] The still more complex combinations--which are so clearly expressed
in the crystallo-hydrates, double salts, and similar
compounds--although they may be regarded as independent, are,
however, most easily understood with our present knowledge as
aggregations of whole molecules to which there are no corresponding
double compounds, containing one atom of an element R and many
atoms of other elements RX_{_n_}. The above types embrace all cases
of direct combinations of atoms, and the formula MgSO_{4},7H_{2}O
cannot, without violating known facts, be directly deduced from the
types MgX_{_n_} or SX_{_n_}, whilst the formula MgSO_{4}
corresponds both with the type of the magnesium compounds MgX_{2}
and with the type of the sulphur compounds SO_{2}X_{2}, or in
general SX_{6}, where X_{2} is replaced by (OH)_{2}, with the
substitution in this case of H_{2} by the atom Mg, which always
replaces H_{2}. However, it must be remarked that the sodium
crystallo-hydrates often contain 10H_{2}O, the magnesium
crystallo-hydrates 6 and 7H_{2}O, and that the type PtM_{2}X_{6} is
proper to the double salts of platinum, &c. With the further
development of our knowledge concerning crystallo-hydrates, double
salts, alloys, solutions, &c., in the _chemical sense_ of feeble
compounds (that is, such as are easily destroyed by feeble chemical
influences) it will probably be possible to arrive at a perfect
generalisation for them. For a long time these subjects were only
studied by the way or by chance; our knowledge of them is
accidental and destitute of system, and therefore it is impossible
to expect as yet any generalisation as to their nature. The days of
Gerhardt are not long past when only three types were recognised:
RX, RX_{2}, and RX_{3}; the type RX_{4} was afterwards added (by
Cooper, Kekulé, Butleroff, and others), mainly for the purpose of
generalising the data respecting the carbon compounds. And indeed
many are still satisfied with these types, and derive the higher
types from them; for instance, RX_{5} from RX_{3}--as, for example,
POCl_{3} from PCl_{3}, considering the oxygen to be bound both to
the chlorine (as in HClO) and to the phosphorus. But the time has
now arrived when it is clearly seen that the forms RX, RX_{2},
RX_{3}, and RX_{4} do not exhaust the whole variety of phenomena.
The revolution became evident when Würtz showed that PCl_{5} is not
a compound of PCl_{3} + Cl_{2} (although it may decompose into
them), but a whole molecule capable of passing into vapour, PCl_{5}
like PF_{5} and SiF_{4}. The time for the recognition of types even
higher than RX_{8} is in my opinion in the future; that it will
come, we can already see in the fact that oxalic acid,
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