The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Let X be chlorine or hydrogen. Then as examples of the first type we
have: H_{2}, Cl_{2}, HCl, KCl, NaCl, &c. The compounds of oxygen or
calcium may serve as examples of the type RX_{2}: OH_{2}, OCl_{2}, OHCl,
CaO, Ca(OH)_{2}, CaCl_{2}, &c. For the third type RX_{3} we know the
representative NH_{3} and the corresponding compounds N_{2}O_{3}, NO(OH),
NO(OK), PCl_{3}, P_{2}O_{3}, PH_{3}, SbH_{3}, Sb_{2}O_{3}, B_{2}O_{3},
BCl_{3}, Al_{2}O_{3}, &c. The type RX_{4} is known among the hydrogen
compounds. Marsh gas, CH_{4}, and its corresponding saturated
hydrocarbons, C_{_n_}H_{2_n_ + 2}, are the best representatives. Also
CH_{3}Cl, CCl_{4}, SiCl_{4}, SnCl_{4}, SnO_{2}, CO_{2}, SiO_{2}, and a
whole series of other compounds come under this class. The type RX_{5} is
also already familiar to us, but there are no purely hydrogen compounds
among its representatives. Sal-ammoniac, NH_{4}Cl, and the corresponding
NH_{4}(OH), NO_{2}(OH), ClO_{2}(OK), as well as PCl_{5}, POCl_{3}, &c.,
are representatives of this type. In the higher types also there are no
hydrogen compounds, but in the type RX_{6} there is the chlorine compound
WCl_{6}. However, there are many oxygen compounds, and among them SO_{3}
is the best known representative. To this class also belong
SO_{2}(OH)_{2}, SO_{2}Cl_{2}, SO_{2}(OH)Cl, CrO_{3}, &c., all of an acid
character. Of the higher types there are in general only oxygen and acid
representatives. The type RX_{7} we know in perchloric acid, ClO_{3}(OH),
and potassium permanganate, MnO_{3}(OK), is also a member. The type
RX_{8} in a free state is very rare; osmic anhydride, OsO_{4}, is the
best known representative of it.[6]
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