The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[42] Among the other compounds of antimony, _antimoniuretted hydrogen_,
SbH_{3}, resembles arseniuretted hydrogen in its mode of formation
and properties (it splits up at 150°, Brunn 1890; when liquified,
it boils at -65° and solidifies at -92°), whilst the halogen
compounds differ in many respects from those of arsenic. When
chlorine is passed over an excess of antimony powder, it forms
_antimony trichloride_, SbCl_{3}, but if the chlorine be in excess
it forms the _pentachloride_, SbCl_{5}. The trichloride is a
crystalline substance which melts at 72° and distils at 230°,
whilst the pentachloride is a yellow liquid, which splits up into
chlorine and the trichloride when heated; at 140° it begins to
give off chlorine abundantly, carrying away the vapour of the
trichloride with it; and at 200° the decomposition is complete,
and pure antimonious chloride only passes over. This property of
antimony pentachloride has caused it to be applied in many cases
for the transference of chlorine; all the more that when it has
given up its chlorine, it leaves the trichloride, which is able to
absorb a fresh amount of chlorine; and therefore many substances
which are unable to react directly with gaseous chlorine do so
with antimony pentachloride, and in the presence of a small
quantity of it chlorine will act on them, just as oxygen is able,
in the presence of nitrogen oxides, to oxidise substances which
could not be oxidised by means of free oxygen. Thus carbon
bisulphide is not acted on by chlorine at low temperatures--this
reaction requires a high temperature--but in the presence of
antimony pentachloride its conversion into carbon tetrachloride
takes place at low temperatures. Antimony tri- and pentachloride,
having the character of chloranhydrides, fume in air, attract
moisture, and are decomposed by water, forming antimonious and
antimonic acids. But in the first action of water the trichloride
does not evolve all its chlorine as hydrochloric acid, which is
intelligible in view of the fact that antimonious anhydride is
also a base, and is therefore able to react with acids; indeed
antimony sulphide dissolved in an excess of hydrochloric acid
(hydrogen sulphide is evolved) gives an aqueous solution of
antimony trichloride, which, when carefully distilled, even gives
the anhydrous compound. Antimony trichloride is only decomposed by
an excess of water, and then not completely, for with a large
quantity of water it forms _powder of algaroth_--_i.e._ antimony
oxychloride. The first action of water consists in the formation
of _oxychloride_, SbOCl--that is, a salt corresponding to oxide of
antimony as a base. If antimony oxide or antimony chloride be
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