The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
elements presently to be described.[7]
[7] The hydrogen compounds, R_{2}H, in equivalency correspond with the
type of the suboxides, R_{4}O. Palladium, sodium, and potassium
give such hydrogen compounds, and it is worthy of remark that
according to the periodic system these elements stand near to each
other, and that in those groups where the hydrogen compounds R_{2}H
appear, the quaternary oxides R_{4}O are also present.
Not wishing to complicate the explanation, I here only touch on the
general features of the relation between the hydrates and oxides
and of the oxides among themselves. Thus, for instance, the
conception of the ortho-acids and of the normal acids will be
considered in speaking of phosphoric and phosphorous acids.
As in the further explanation of the periodic law only those oxides
which give salts will be considered, I think it will not be
superfluous to mention here the following facts relative to the
peroxides. Of the _peroxides_ corresponding with hydrogen peroxide,
the following are at present known: H_{2}O_{2}, Na_{2}O_{2},
S_{2}O_{7} (as HSO_{4}?), K_{2}O_{4}, K_{2}O_{2}, CaO_{2}, TiO_{3},
Cr_{2}O_{7}, CuO_{2}(?), ZnO_{2}, Rb_{2}O_{2}, SrO_{2},
Ag_{2}O_{2}, CdO_{2}, CsO_{2}, Cs_{2}O_{2}, BaO_{2}, Mo_{2}O_{7},
SnO_{3}, W_{2}O_{7}, UO_{4}. It is probable that the number of
peroxides will increase with further investigation. A periodicity
is seen in those now known, for the elements (excepting Li) of the
first group, which give R_{2}O, form peroxides, and then the
elements of the sixth group seem also to be particularly inclined
to form peroxides, R_{2}O_{7}; but at present it is too early, in
my opinion, to enter upon a generalisation of this subject, not
only because it is a new and but little studied matter (not
investigated for all the elements), but also, and more especially,
because in many instances only the hydrates are known--for
instance, Mo_{2}H_{2}O_{8}--and they perhaps are only compounds of
peroxide of hydrogen--for example, Mo_{2}H_{2}O_{8} = 2MoO_{3} +
H_{2}O_{2}--since Prof. Schöne has shown that H_{2}O_{2} and
BaO_{2} possess the property of combining together and with other
oxides. Nevertheless, I have, in the general table expressing the
periodic properties of the elements, endeavoured to sum up the data
respecting all the known peroxide compounds whose characteristic
property is seen in their capability to form peroxide of hydrogen
under many circumstances.
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