The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In the preceding we see not only the regularity and simplicity which
govern the formation and properties of the oxides and of all the
compounds of the elements, but also a fresh and exact means for
recognising the analogy of elements. Analogous elements give compounds of
analogous types, both higher and lower. If CO_{2} and SO_{2} are two
gases which closely resemble each other both in their physical and
chemical properties, the reason of this must be looked for not in an
analogy of sulphur and carbon, but in that identity of the type of
combination, RX_{4}, which both oxides assume, and in that influence
which a large mass of oxygen always exerts on the properties of its
compounds. In fact, there is little resemblance between carbon and
sulphur, as is seen not only from the fact that CO_{2} is the _higher
form_ of oxidation, whilst SO_{2} is able to further oxidise into SO_{3},
but also from the fact that all the other compounds--for example, SH_{2}
and CH_{4}, SCl_{2} and CCl_{4}, &c.--are entirely unlike both in type
and in chemical properties. This absence of analogy in carbon and sulphur
is especially clearly seen in the fact that the highest saline oxides are
of different composition, CO_{2} for carbon, and SO_{3} for sulphur. In
Chapter VIII. we considered the limit to which carbon tends in its
compounds, and in a similar manner there is for every element in its
compounds a tendency to attain a certain highest limit RX_{_n_}. This
view was particularly developed in the middle of the present century by
Frankland in studying the metallo-organic compounds, _i.e._ those in
which X is wholly or partially a hydrocarbon radicle; for instance, X =
CH_{3} or C_{2}H_{5} &c. Thus, for example, antimony, Sb (Chapter XIX.)
gives, with chlorine, compounds SbCl_{3} and SbCl_{5} and corresponding
oxygen compounds Sb_{2}O_{3} and Sb_{2}O_{5}, whilst under the action of
CH_{3}I, C_{2}H_{5}I, or in general EI (where E is a hydrocarbon radicle
of the paraffin series), upon antimony or its alloy with sodium there are
formed SbE_{3} (for example, Sb(CH_{3})_{3}, boiling at about 81°),
which, corresponding to the lower form of combination SbX_{3}, are able
to combine further with EI, or Cl_{2}, or O, and to form compounds of the
limiting type SbX_{5}; for example, SbE_{4}Cl corresponding to NH_{4}Cl
with the substitution of nitrogen by antimony, and of hydrogen by the
hydrocarbon radicle. The elements which are most chemically analogous are
characterised by the fact of their giving compounds of similar form
RX_{_n_}. The halogens which are analogous give both higher and lower
compounds. So also do the metals of the alkalis and of the alkaline
earths. And we saw that this analogy extends to the composition and
properties of the nitrogen and hydrogen compounds of these metals, which
is best seen in the salts. Many such groups of analogous elements have
long been known. Thus there are analogues of oxygen, nitrogen, and
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