The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The essence of the matter is seen in these groups. The halogens have
smaller atomic weights than the alkali metals, and the latter than the
metals of the alkaline earths. Therefore, _if all the elements be
arranged in the order of their atomic weights, a periodic repetition of
properties is obtained_. This is expressed by the _law of periodicity_,
_the properties of the elements, as well as the forms and properties of
their compounds, are in periodic dependence or (expressing ourselves
algebraically) form a periodic function of the atomic weights of the
elements_.[8] Table I. of _the periodic system of the elements_, which is
placed at the very beginning of this book, is designed to illustrate this
law. It is arranged in conformity with the eight types of oxides
described in the preceding pages, and those elements which give the
oxides, R_{2}O and consequently salts RX, form the 1st group; the
elements giving R_{2}O_{2} or RO as their highest grade of oxidation
belong to the 2nd group; those giving R_{2}O_{3} as their highest oxides
form the 3rd group, and so on; whilst the elements of all the groups
which are nearest in their atomic weights are arranged in series from 1
to 12. The even and uneven series of the same groups present the same
forms and limits, but differ in their properties, and therefore two
contiguous series, one even and the other uneven--for instance, the 4th
and 5th--form a period. Hence the elements of the 4th, 6th, 8th, 10th,
and 12th, or of the 3rd, 5th, 7th, 9th, and 11th, series form analogues,
like the halogens, the alkali metals, &c. The conjunction of two series,
one even and one contiguous uneven series, thus forms one large _period_.
These periods, beginning with the alkali metals, end with the halogens.
The elements of the first two series have the lowest atomic weights, and
in consequence of this very circumstance, although they bear the general
properties of a group, they still show many peculiar and independent
properties.[9] Thus fluorine, as we know, differs in many points from the
other halogens, and lithium from the other alkali metals, and so on.
These lightest elements may be termed _typical elements_. They include--
H.
Li, Be, B, C, N, O, F.
Na, Mg....
In the annexed table all the remaining elements are arranged, not in
groups and series, but _according to periods_. In order to understand the
essence of the matter, it must be remembered that here the atomic weight
gradually increases along a given line; for instance, in the line
commencing with K = 39 and ending with Br = 80, the intermediate elements
have intermediate atomic weights, as is clearly seen in Table III., where
the elements stand in the order of their atomic weights.
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