The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
I. II. III. IV. V. VI. VII. I. II. III. IV. V. VI. VII.
{ Even Series. } Mg Al Si P S Cl
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br
Rb Sr Y Zr Nb Mo -- Ru Rh Pd Ag Cd In Sn Sb Te I
Cs Ba La Ce Di? -- -- -- -- -- -- -- -- -- -- -- --
-- -- Yb -- Ta W -- Os Ir Pt Au Hg Tl Pb Bi -- --
-- -- -- Th -- U { Uneven Series }
The same degree of analogy that we know to exist between potassium,
rubidium, and cæsium; or chlorine, bromine, and iodine; or calcium,
strontium, and barium, also exists between the elements of the other
vertical columns. Thus, for example, zinc, cadmium, and mercury, which
are described in the following chapter, present a very close analogy with
magnesium. For a true comprehension of the matter[10] it is very
important to see that all the aspects of the distribution of the elements
according to their atomic weights essentially express one and the same
fundamental _dependence_--_periodic properties_.[11] The following points
then must be remarked in it.
[8] The periodic law and the periodic system of the elements appeared
in the same form as here given in the first edition of this work,
begun in 1868 and finished in 1871. In laying out the accumulated
information respecting the elements, I had occasion to reflect on
their mutual relations. At the beginning of 1869 I distributed
among many chemists a pamphlet entitled 'An Attempted System of the
Elements, based on their Atomic Weights and Chemical Analogies,'
and at the March meeting of the Russian Chemical Society, 1869, I
communicated a paper 'On the Correlation of the Properties and
Atomic Weights of the Elements.' The substance of this paper is
embraced in the following conclusions: (1) The elements, if
arranged according to their atomic weights, exhibit an evident
_periodicity_ of properties. (2) Elements which are similar as
regards their chemical properties have atomic weights which are
either of nearly the same value (platinum, iridium, osmium) or
which increase regularly (_e.g._ potassium, rubidium, cæsium). (3)
The arrangement of the elements or of groups of elements in the
order of their atomic weights corresponds with their so-called
_valencies_. (4) The elements, which are the most widely
distributed in nature, have _small_ atomic weights, and all the
elements of small atomic weight are characterised by sharply
defined properties. They are therefore typical elements. (5) The
_magnitude_ of the atomic weight determines the character of an
element. (6) The discovery of many yet unknown elements may be
expected. For instance, elements analogous to aluminium and
silicon, whose atomic weights would be between 65 and 75. (7) The
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