The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
conception of atoms and molecules which combine in multiple
proportions, with intervals (not continuously), it _above all_
depends on there being but few types of compounds, which are
arithmetically simple, _repeat themselves_, and offer no
uninterrupted transitions, so that each period can only contain a
definite number of members. For this reason there can be no other
elements between magnesium, which gives the chloride MgCl_{2}, and
aluminium, which forms AlX_{3}; there is a break in the
continuity, according to the law of multiple proportions. The
periodic law ought not, therefore, to be expressed by geometrical
figures in which continuity is always understood. Owing to these
considerations I never have and never will express the periodic
relations of the elements by any geometrical figures. (2) _By a
plane spiral._ Radii are traced from a centre, proportional to the
atomic weights; analogous elements lie along one radius, and the
points of intersection are arranged in a spiral. This method,
adopted by De Chancourtois, Baumgauer, E. Huth, and others, has
many of the imperfections of the preceding, although it removes
the indefiniteness as to the number of elements in a period. It is
merely an attempt to reduce the complex relations to a simple
graphic representation, since the equation to the spiral and the
number of radii are not dependent upon anything. (3) _By the lines
of atomicity_, either parallel, as in Reynolds's and the Rev. S.
Haughton's method, or as in Crookes's method, arranged to the
right and left of an axis, along which the magnitudes of the
atomic weights are counted, and the position of the elements
marked off, on the one side the members of the even series
(paramagnetic, like oxygen, potassium, iron), and on the other
side the members of the uneven series (diamagnetic, like sulphur,
chlorine, zinc, and mercury). On joining up these points a
periodic curve is obtained, compared by Crookes to the
oscillations of a pendulum, and, according to Haughton,
representing a cubical curve. This method would be very graphic
did it not require, for instance, that sulphur should be
considered as bivalent and manganese as univalent, although
neither of these elements gives stable derivatives of these
natures, and although the one is taken on the basis of the lowest
possible compound SX_{2}, and the other of the highest, because
manganese can be referred to the univalent elements only by the
analogy of KMnO_{4} to KClO_{4}. Furthermore, Reynolds and Crookes
place hydrogen, iron, nickel, cobalt, and others outside the axis
of atomicity, and consider uranium as bivalent without the least
foundation.
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