The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In concluding this historical statement I consider it well to
observe that no law of nature, however general, has been
established all at once; its recognition is always preceded by many
hints; the establishment of a law, however, does not take place
when its significance is recognised, but only when it has been
confirmed by experiment, which the man of science must consider as
the only proof of the correctness of his conjectures and opinions.
I therefore, for my part, look upon Roscoe, De Boisbaudran, Nilson,
Winkler, Brauner, Carnelley, Thorpe, and others who verified the
adaptability of the periodic law to chemical facts, as the true
founders of the periodic law, the further development of which
still awaits fresh workers.
[9] This resembles the fact, well known to those having an acquaintance
with organic chemistry, that in a series of homologues (Chapter
VIII.) the first members, in which there is the least carbon,
although showing the general properties of the homologous series,
still present certain distinct peculiarities.
[10] Besides arranging the elements (_a_) in a successive order
according to their atomic weights, with indication of their
analogies by showing some of the properties--for instance, their
power of giving one or another form of combination--both of the
_elements_ and of their compounds (as is done in Table III. and in
the table on p. 36), (_b_) according to periods (as in Table I. at
the commencement of volume I. after the preface), and (_c_)
according to groups and series or small periods (as in the same
tables), I am acquainted with the following methods of expressing
the periodic relations of the elements: (1) By a curve drawn
through points obtained in the following manner: The elements are
arranged along the horizontal axis as abscissæ at distances from
zero proportional to their atomic weights, whilst the values for
all the elements of some property--for example, the specific
volumes or the melting points, are expressed by the ordinates.
This method, although graphic, has the theoretical disadvantage
that it does not in any way indicate the existence of a limited
and definite number of elements in each period. There is nothing,
for instance, in this method of expressing the law of periodicity
to show that between magnesium and aluminium there can be no other
element with an atomic weight of, say, 25, atomic volume 13, and
in general having properties intermediate between those of these
two elements. The actual periodic law does not correspond with a
continuous change of properties, with a continuous variation of
atomic weight--in a word, it does not express an uninterrupted
function--and as the law is purely chemical, starting from the
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