The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
hypothesis of the building up of all the elements from one primary
matter, and at the present time such an hypothesis has not the
least support either in theory or in fact. Besides which the
starting-point of the theory is the specific gravity of the metals
at a definite temperature (it is not known how the above relation
would appear at other temperatures), and the specific gravity
varies even under mechanical influences. L. Hugo (1884)
endeavoured to represent the atomic weights of Li, Na, K, Rb, and
Cs by geometrical figures--for instance, Li = 7 represents a
central atom = 1 and six atoms on the six terminals of an
octahedron; Na, is obtained by applying two such atoms on each
edge of an octahedron, and so on. It is evident that such methods
can add nothing new to our data respecting the atomic weights of
analogous elements.
[11] Many natural phenomena exhibit a dependence of a periodic
character. Thus the phenomena of day and night and of the seasons
of the year, and vibrations of all kinds, exhibit variations of a
periodic character in dependence on time and space. But in
ordinary periodic functions one variable varies continuously,
whilst the other increases to a limit, then a period of decrease
begins, and having in turn reached its limit a period of increase
again begins. It is otherwise in the periodic function of the
elements. Here the mass of the elements does not increase
continuously, but abruptly, by steps, as from magnesium to
aluminium. So also the valency or atomicity leaps directly from 1
to 2 to 3, &c., without intermediate quantities, and in my opinion
it is these properties which are the most important, and it is
their periodicity which forms the substance of the periodic law.
It expresses _the properties of the real elements_, and not of
what may be termed their manifestations visually known to us. The
external properties of elements and compounds are in periodic
dependence on the atomic weight of the elements only because these
external properties are themselves the result of the properties of
the real elements which unite to form the 'free' elements and the
compounds. To explain and express the periodic law is to explain
and express the cause of the law of multiple proportions, of the
difference of the elements, and the variation of their atomicity,
and at the same time to understand what mass and gravitation are.
In my opinion this is still premature. But just as without knowing
the cause of gravitation it is possible to make use of the law of
gravity, so for the aims of chemistry it is possible to take
advantage of the laws discovered by chemistry without being able
to explain their causes.
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