The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The above-mentioned peculiarity of the
laws of chemistry respecting definite compounds and the atomic
weights leads one to think that the time has not yet come for
their full explanation, and I do not think that it will come
before the explanation of such a primary law of nature as the law
of gravity.
It will not be out of place here to turn our attention to the
many-sided correlation existing between the undecomposable
_elements and the compound carbon radicles_, which has long been
remarked (Pettenkofer, Dumas, and others), and reconsidered in
recent times by Carnelley (1886), and most originally in
Pelopidas's work (1883) on the principles of the periodic system.
Pelopidas compares the series containing eight hydrocarbon
radicles, C_{_n_}H_{2_n_ + 1}, C_{_n_}H_{2_n_} &c., for instance,
C_{6}H_{13}, C_{6}H_{12}, C_{6}H_{11}, C_{6}H_{10}, C_{6}H_{9},
C_{6}H_{8}, C_{6}H_{7}, and C_{6}H_{6}--with the series of the
elements arranged in eight groups. The analogy is particularly
clear owing to the property of C_{_n_}H_{2_n_+1} to combine with
X, thus reaching saturation, and of the following members with
X_{2}, X_{3} ... X_{8}, and especially because these are followed
by an aromatic radicle--for example, C_{6}H_{5}--in which, as is
well known, many of the properties of the saturated radicle
C_{6}H_{13} are repeated, and in particular the power of forming a
univalent radicle again appears. Pelopidas shows a confirmation of
the parallel in the property of the above radicles of giving
oxygen compounds corresponding with the groups in the periodic
system. Thus the hydrocarbon radicles of the first group--for
instance, C_{6}H_{13} or C_{6}H_{5}--give oxides of the form
R_{2}O and hydroxides RHO, like the metals of the alkalis; and in
the third group they form oxides R_{2}O_{3} and hydrates RO_{2}H.
For example, in the series CH_{3} the corresponding compounds of
the third group will be the oxide (CH)_{2}O_{3} or
C_{2}H_{2}O_{3}--that is, formic anhydride and hydrate, CHO_{2}H,
or formic acid. In the sixth group, with a composition of C_{2},
the oxide RO_{3} will be C_{2}O_{3}, and hydrate
C_{2}H_{2}O_{4}--that is, also a bibasic acid (oxalic) resembling
sulphuric, among the inorganic acids. After applying his views to
a number of organic compounds, Pelopidas dwells more particularly
on the radicles corresponding with ammonium.
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