The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Ba_{2}O_{2} 5·7 52 - 10
La_{2}O_{3} 6·5 50 + 1
Ce_{2}O_{4} 6·74 50 + 2
Ta_{2}O_{5} 7·5 59 + 4·6
W_{2}O_{6} 6·8 68 + 8·2
Hg_{2}O_{2} 11·1 39 + 4·5
Pb_{2}O_{4} 8·9 53 + 4·2
Th_{2}O_{4} 9·86 54 + 2
As the volumes of the chlorides, organo-metallic and all other
corresponding compounds, also vary in a like periodic succession with a
change of elements, it is evidently possible to indicate the properties
of substances yet uninvestigated by experimental means, and even those of
yet undiscovered elements. It was possible by following this method to
foretell, on the basis of the periodic law, many of the properties of
scandium, gallium, and germanium, which were verified with great accuracy
after these metals had been discovered.[23] The periodic law, therefore,
has not only embraced the mutual relations of the elements and expressed
their analogy, but has also to a certain extent subjected to law the
doctrine of the types of the compounds formed by the elements: it has
enabled us to see a regularity in the variation of all chemical and
physical properties of elements and compounds, and has rendered it
possible to foretell the properties of elements and compounds yet
uninvestigated by experimental means; thus it has prepared the ground for
the building up of atomic and molecular mechanics.[24]
[23] As an example we will take indium oxide, In_{2}O_{3}. Its sp. gr.
and sp. vol. should be the mean of those of cadmium oxide,
Cd_{2}O_{2}, and stannic oxide, Sn_{2}O_{4}, as indium stands
between cadmium and tin. Thus in the seventies it was already
evident that the volume of indium oxide should be about 38, and
its sp. gr. about 7·2, which was confirmed by the determinations
of Nilson and Pettersson (7·179) made in 1880.
[24] As the distance between, and the volumes of, the molecules and
atoms of solids and liquids certainly enter into the data for the
solution of the problems of molecular mechanics, which as yet have
only been worked out to any extent for the gaseous state, the
study of the specific gravity of solids, and especially of
liquids, has long had an extensive literature. With respect to
solids, however, a great difficulty is met with, owing to the
specific gravity varying not only with a change of isomeric state
(for example, for silica in the form of quartz = 2·65, and in
tridymite = 2·2) but also directly under mechanical pressure (for
example, in a crystalline, cast, and forged metal), and even with
the extent to which they are powdered, &c., which influences are
imperceptible in liquids. Compare Chapter XIV., Note 55^{bis}.
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