The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Without going into further details, we may add to what has been
said above that the conception of specific volumes and atomic
distances has formed the subject of a large number of researches,
but as yet it is only possible to lay down a few generalisations
given by Dumas, Kopp, and others, which are mentioned and
amplified by me in my work cited in Note 20, and in my memoirs on
this subject.
1. Analogous compounds and their isomorphs have frequently
approximately the same molecular volumes.
2. Other compounds, analogous in their properties, exhibit
molecular volumes which increase with the molecular weight.
3. When a contraction takes place in combination in a gaseous
state, then contraction is in the majority of instances also to be
observed in the solid or liquid state--that is, the sum of the
volumes of the reacting substances is greater than the volume of
the resultant substance or substances.
4. In decomposition the reverse takes place to that which occurs
in combination.
5. In substitution (when the volumes in a state of vapour do not
vary) a very small change of volume generally takes place--that
is, the sum of the volumes of the reacting substances is almost
equal to the sum of the resultant substances.
6. Hence it is impossible to judge the volume of the component
substances from the volume of a compound, although it is possible
to do so from the product of substitution.
7. The replacement of H_{2} by sodium, Na_{2}, and by barium, Ba,
as well as the replacement of SO_{4} by Cl_{2}, scarcely changes
the volume, but the volume increases with the replacement of Na by
K, and decreases with the replacement of H_{2}, by Li_{2} Cu, and
Mg.
8. There is no need for comparing volumes in a solid and liquid
state at the so-called corresponding temperatures--that is at
temperatures at which vapour tension is equal in each case. The
comparison of volumes at the ordinary temperature is sufficient
for finding a regularity in the relations of volumes (this
deduction was developed with particular detail by me in 1856).
9. Many investigators (Perseau, Schröder, Löwig, Playfair and
Joule, Baudrimont, Einhardt) have sought in vain for a multiple
proportion in the specific volumes of solids and liquids.
10. The truth of the above is seen very clearly in comparing the
volumes of polymeric substances. The volumes of their molecules
are equal in a state of vapour, but are very different in a solid
and liquid state, as is seen from the close resemblance of the
specific gravities of polymeric substances. But as a rule the more
complex polymerides are denser than the simpler.
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