The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
11. We know that the hydroxides of light metals have generally a
smaller volume than the metals, whilst that of magnesium hydroxide
is considerably greater, which is explained by the stability of
the former and instability of the latter. In proof of this we may
cite, besides the volumes of the true alkali metals, the volume of
barium (36) which is greater than that of its stable hydroxide
(sp. gr. 4·5, sp. vol. 30). The volumes of the salts of magnesium
and calcium are greater than the volume of the metal, with the
single exception of the fluoride of calcium. With the heavy metals
the volume of the compound is always greater than the volume of
the metal, and, moreover, for such compounds as silver iodide, AgI
(_d_ = 5·7), and mercuric iodide, HgI_{2} (_d_ = 6·2, and the
volumes of the compounds 41 and 73), the volume of the compound is
greater than the sum of the volumes of the component elements.
Thus the sum of the volumes Ag + I = 36, and the volume of AgI =
41. This stands out with particular clearness on comparing the
volumes K + I = 71 with the volume of KI, which is equal to 54,
because its density = 3·06.
12. In such combinations, between solids and liquids, as
solutions, alloys, isomorphous mixtures, and similar feeble
chemical compounds, the sum of the reacting substances is always
very nearly that of the resulting substance, but here the volume
is either slightly larger or smaller than the original; speaking
generally, the amount of contraction depends on the force of
affinity acting between the combining substances. I may here
observe that the present data respecting the specific volumes of
solid and liquid bodies deserve a fresh and full elaboration to
explain many contradictory statements which have accumulated on
this subject.
CHAPTER XVI
ZINC, CADMIUM, AND MERCURY
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