The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
These three metals give, like magnesium, oxides RO, which form feebly
energetic bases, and like magnesium they are volatile. The volatility
increases with the atomic weight. Magnesium can be distilled at a white
heat, zinc at a temperature of about 930°, cadmium about 770°, and
mercury about 351°. Their oxides, RO, are more easily reducible than
magnesia, and mercuric oxide is the most easily reducible. The properties
of their salts RX_{2} are very similar to the properties of MgX_{2}.
Their solubility, power of forming double and basic salts, and many other
qualities are in many respects identical with those of MgX_{2}. The
greater or less ease with which they are oxidised, the instability of
their compounds, the density of the metals and their compounds, their
scarcity in nature, and many other properties gradually change with the
increase of atomic weight, as might be expected from the periodicity of
the elements. Their principal characteristics, as contrasted with
magnesium, find a general expression in the fact that zinc, cadmium, and
mercury are heavy metals.
_Zinc_ stands nearest to magnesium in atomic weight and in properties.
Thus zinc sulphate, or white vitriol, easily crystallises with seven
molecules of water, ZnSO_{4},7H_{2}O. It is isomorphous with Epsom salts,
and parts with difficulty with the last molecule of water; it forms
double salts--for instance, ZnK_{2}(SO_{4})_{2},6H_{2}O--exactly as
magnesium sulphate does.[1] _Zinc oxide_, ZnO, is a white powder, almost
insoluble in water,[2] like magnesia, from which, however, it is
distinguished by its solubility in solutions of sodium and potassium
hydroxides.[3] Zinc chloride[4] is decomposed by water, combines with
ammonium chloride, potassium chloride, &c., just like magnesium chloride,
forms an oxychloride, and also combines with zinc oxide.[4 bis]
[1] Zinc sulphate is often obtained as a by-product--for instance, in
the action of galvanic batteries containing zinc and sulphuric
acid. When the anhydrous salt is heated it forms zinc oxide,
sulphurous anhydride, and oxygen. The solubility in 100 parts of
water at O° = 43, 20° = 53, 40° = 63-1/2, 60° = 74, 80° = 84-1/2,
100° = 95 parts of anhydrous zinc sulphate--that is to say, it is
closely expressed by the formula 43 + 0·52_t_.
An admixture of iron is often found in ordinary sulphate of zinc in
the form of ferrous sulphate, FeSO_{4}, isomorphous with the zinc
sulphate. In order to separate it, chlorine is passed through the
solution of the impure salt (when the ferrous salt is converted
into ferric), the solution is then boiled, and zinc oxide is
afterwards added, which, after some time has elapsed, precipitates
all the ferric oxide. Ferric oxide of the form R_{2}O_{3} is
displaced by zinc oxide of the form RO.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account