The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[2] Zinc oxide is obtained both by the combustion and oxidation of
zinc, and by the ignition of some of its salts--for instance, those
of carbonic and nitric acids; it is likewise precipitated by
alkalis from a solution of ZnX_{2} in the form of a gelatinous
hydroxide. The oxide produced by roasting zinc blende (by burning
in the air, when the sulphur is converted into sulphurous
anhydride) contains various impurities. For purification, the oxide
is mixed with water, and the sulphurous anhydride formed by
roasting the blende is passed through it. Zinc bisulphite,
ZnSO_{3},H_{2}SO_{3}, then passes into solution. If a solution of
this salt be evaporated, and the residue ignited, zinc oxide, free
from many of its impurities, will remain. Zinc oxide is a light
white powder, used as a paint instead of _white lead_; the basic
salt, corresponding with magnesia alba, is used for the same
purpose. V. Kouriloff (1890) by boiling the hydrate of the oxide
with a 3 p.c. solution of peroxide of hydrogen obtained
Zn_{2}H_{2}O_{4} or the hydrate of the peroxide
(= ZnO_{2}ZnH_{2}O_{2} or a compound of 2ZnO with H_{2}O_{2}),
which did not part with its oxygen at 100°, but only above 120°.
Cadmium gives a similar compound of a yellow colour. Magnesium,
although it does form such a compound, does so with great
difficulty.
[3] For the solution of one part of the oxide 55,400 parts of water are
required. Nevertheless, even in such a weak solution, zinc oxide
(hydroxide, ZnH_{2}O_{2}) changes the colour of red litmus paper.
Zinc oxide is obtained in the wet way by adding an alkali hydroxide
to a solution of a zinc salt--for instance: ZnSO_{4} + 2HKO =
K_{2}SO_{4} + ZnH_{2}O_{2}. The gelatinous precipitate of zinc
hydroxide is _soluble_ in an excess of alkali, which clearly
distinguishes it from magnesia. This solubility of zinc hydroxide
in alkalis is due to the power of zinc oxide to form a compound,
although an unstable one, with alkalis--that is to say, points to
the fact that zinc oxide already partly belongs to the intermediate
oxides. The oxides of the metals above mentioned (except BeO) do
not show this property. The property which metallic zinc itself has
of dissolving in caustic alkali with the disengagement of hydrogen
(the solution is facilitated by contact with platinum or iron)
depends on the formation of such a compound of the oxides of zinc
and the alkali metals. The solution of zinc hydroxide,
ZnH_{2}O_{2}, in potash (in a strong solution), proceeds when these
hydrates are taken in proportion to ZnH_{2}O_{2} + KHO. If such a
solution be evaporated to dryness, water extracts only caustic
potash from the fused residue. When a solution of zinc hydroxide in
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