The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In consequence of the complex character of the phenomenon, the
authors themselves do not consider their determinations as being
conclusive, and only give them a relative significance; and in
this connection it is remarkable that hydrobromic acid under
similar conditions (with an equivalent strength) gives a greater
(from 2 to 5 times) rapidity of action than hydrochloric acid, but
sulphuric acid a far smaller velocity (nearly 25 times smaller).
It is also remarkable that during the reaction the metal becomes
much more heated than the acid.
It may be mentioned that zinc dust and zinc itself, when heated
with hydrated lime and similar hydrates, disengages hydrogen: this
method has even been proposed for obtaining hydrogen for filling
war balloons.
The action of zinc on acids, and the consequent formation of zinc
salts, interferes with its application in many cases, particularly for
the preservation of liquids either containing or capable of developing
acid. For this reason zinc vessels ought not to be used for the
preparation or preservation of food, as this often contains acids which
form poisonous salts with the zinc. Even ordinary water, containing
carbonic acid, slowly attacks zinc.
Finely divided zinc, or _zinc dust_, obtained in the distillation of the
metal when the receiver is not heated up to the melting point, on account
of its presenting a large surface of contact and containing foreign
matter (particularly zinc oxide), has in the highest degree the property
of decomposing acids, and even water, which it easily decomposes,
particularly if slightly heated. On this account zinc dust is often used
in laboratories and factories as a reducing agent. A similar influence of
the finely divided state is also noticed in other metals--for instance,
copper and silver--which again shows the close connection between
chemical and physico-mechanical phenomena. We must first of all turn to
this close connection for an explanation of the widely spread application
of zinc in galvanic batteries, where the chemical (latent, potential)
energy of the acting substances is transformed into (evident, kinetic)
galvanic energy, and through this latter into heat, light, or mechanical
work.
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