The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Hermann and Stromeyer, in 1819, showed that _cadmium_ is almost always
found with zinc, and in many respects resembles it. When distilled the
cadmium volatilises sooner, because it has a lower boiling point.
Sometimes the zinc dust obtained by the first distillation of zinc
contains as much as 5 per cent. of cadmium. When zinc blende, containing
cadmium, is roasted, the zinc passes into the state of oxide, and the
cadmium sulphide in the ore oxidises into cadmium sulphate, CdSO_{4},
which resists tolerably well the action of heat; therefore if roasted
zinc blende be washed with water, a solution of cadmium sulphate will be
obtained, from which it is very easy to prepare metallic cadmium.
Hydrogen sulphide may be used for separating cadmium from its solutions;
it gives _a yellow precipitate of cadmium sulphide_, CdS (according to
the equation CdSO_{4} + H_{2}S = H_{2}SO_{4} + CdS),[11] which, on
account of its characteristic colour, is used as a pigment.[11 bis]
Cadmium sulphide, when strongly heated in air, leaves cadmium oxide, from
which the metal may be obtained in precisely the same way as in the case
of zinc.
[11] It may be here remarked that sulphate of zinc (especially in the
presence of mineral acids) does not give a precipitate of sulphide
of zinc, or is only slightly precipitated by sulphuretted
hydrogen.
[11 bis] Sulphide of cadmium appears in two varieties of a similar
chemical but different physical character: one is of a lemon
colour, and the other bright red. Kloboukoff (1890) studied the
physical properties of these varieties more closely. The sp. gr.
of the former is 3·906, and of the latter 4·513. They belong to
different crystallographic systems. The first variety may be
converted into the second by friction or pressure, but the second
cannot be converted into the first variety by these means.
Cadmium is a white metal, and when freshly cut is almost as white and
lustrous as tin. It is so soft that it may be easily cut with a knife,
and so malleable that it can be easily drawn into wire, rolled into
sheets, &c. Its specific gravity is 8·67, melting point 320°, boiling
point 770°; its vapours burn, forming a brown powder of the oxide.[12]
Next to mercury it is the most volatile metal; hence Deville determined
the density of its vapours compared with hydrogen, and found it to be
equal to 57·1; therefore the molecule contains _one atom_ whose weight =
112. V. Meyer found the like for zinc; the molecule of mercury also
contains one atom.
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