The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[12] Amongst the compounds of cadmium very closely allied to the
compounds of zinc, we must mention _cadmium iodide_, CdI_{2},
which is used in medicine and photography. This salt crystallises
very well: it is prepared by the direct action of iodine, mixed
with water, on metallic cadmium. One part of cadmium iodide at 20°
requires for its solution 1·08 part of water. It may be remarked
that cadmium chloride at the same temperature requires 0·71 part
of water to dissolve it, so that the iodine compound of this metal
is less soluble than the chloride, whilst the reverse relation
holds in the case of the corresponding compounds of the alkali or
alkaline earthy metals. Cadmium sulphate crystallises well, and
has the composition 3CdSO_{4},8H_{2}O, thus differing from zinc
sulphate.
Cadmium oxide is soluble, although sparingly, in alkalis, but in
the presence of tartaric and certain other acids the alkaline
solution of cadmium oxide does not change when boiled, whilst a
_diluted_ solution in that case deposits cadmium oxide: this may
also serve for separating zinc compounds from those of cadmium.
Cadmium is precipitated from its salts by zinc, which fact may
also be taken advantage of for separating cadmium; for this
reason, in an alloy of zinc and cadmium, acids first of all
extract the zinc. Cadmium is in all respects less energetic than
zinc. Thus, for instance, it decomposes water with difficulty, and
this only when strongly heated. It even acts but slowly on acids,
but then displaces hydrogen from them. It is necessary here to
call attention to the fact that for alkali and alkaline earthy
metals (of the even series) the highest atomic weight determines
the greatest energy; but cadmium (of the uneven series), whilst
having a larger atomic weight than zinc, is less energetic. The
salts of cadmium are colourless, like those of zinc. De Schulten
obtained a crystalline oxychloride, Cd(OH)Cl by heating marble
with a solution of cadmium chloride in a sealed tube at 200°.
_Mercury_ resembles zinc and cadmium in many respects, but
presents that distinction from them which is always noticed in all
the heaviest metals (with regard to atomic weight and density)
compared with the lighter ones--namely, that it oxidises with more
difficulty, and its compounds are more easily decomposed.[12 bis]
Besides compounds of the usual type RX_{2}, it also gives those of
the lower type, RX, which are unknown for zinc and cadmium.[13]
Mercury therefore gives salts of the composition HgX (mercurous
salts) and HgX_{2} (mercuric salts), the oxides having the formulæ
Hg_{2}O and HgO respectively.
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