The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[12 bis] According to its atomic weight, mercury follows gold in the
periodic system, just as cadmium follows silver and zinc follows
copper:--
Ni = 59 Cu = 63 Zn = 65
Pd = 106 Ag = 108 Cd = 112
Pt = 196 Au = 198 Hg = 200
Eventually we shall see the near relation of platinum, palladium,
and nickel, and also of gold, silver, and copper, but we will now
point out the parallelism between these three groups. The relation
between the physical and also chemical properties is here
strikingly similar. Nickel, palladium, and platinum are very
difficult to fuse (far more so than iron, ruthenium, and osmium,
which stand before them). Copper, silver, and gold melt far more
easily in a strong heat than the three preceding metals, and zinc,
cadmium, and mercury melt still more easily. Nickel, palladium,
and platinum are very slightly volatile; copper, silver, and gold
are more volatile; and zinc, cadmium, and mercury are among the
most volatile metals. Zinc oxidises more easily than copper, and
is reduced with more difficulty, and the same is true for mercury
as compared with gold. These properties for cadmium and silver are
intermediate in the respective groups. Relations of this kind
clearly show the nature of the periodic law.
[13] Thus thallium, lead, and bismuth, following mercury according to
their atomic weights, form, besides compounds of the highest
types, TlX_{3}, PbX_{4}, and BiX_{5}, also the lower ones TlX,
PbX_{2}, and BiX_{3}.
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