The Principles of Leather Manufacture — John Shaqi
The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
_Lime_ possesses some antiseptic properties, and is largely used in the
preservation of fleshings before they are sent off to the glue factory.
They are most conveniently stored in a large vat filled with a strong
milk of lime. Dilute solutions of caustic alkalies have an effect
similar to that of lime.
_Common salt_, sodium chloride, NaCl, acts to a certain extent by its
solubility and a dehydrating effect on animal tissues common to
chlorides, which removes water from hides and other materials which it
is used to preserve. Probably the latter characteristic has a good deal
to do with its effect in checking the development of bacteria, since
many species thrive quite well in weak salt solutions, and some even in
brine, and the dehydrating effect of the salt enables it to harden many
animal tissues if used in sufficient quantity, the water they contain
running away in the form of brine.
Ordinary rock salt frequently contains ferric chloride, and this, either
originally present in the salt, or in some cases derived from the action
of the latter upon the iron contained in the blood, is the cause of what
is known as “salt-stains.” These show but little during the liming of
the hides, unless sulphides are used, when stains appear of a greenish
black, from the formation of sulphide of iron; when, however, the hides
come into the tanning liquors, black or blue stains are produced by the
action of the tannin, which are partially removed by the acids of the
liquors during the tanning process, but generally show to some extent in
the finished hide. There is another species of salt-stain, not
apparently due to iron, but to the colouring matter produced by some
fungoid or bacterial growth, which it is practically impossible to
remove, and which is stated to be sometimes caused by the use of old
salt with which hides have been previously salted. Iron stains are most
readily recognised by the use of a solution of potassium ferrocyanide or
thiocyanate slightly acidified by hydrochloric acid. If this be applied
to the leather, the stains will be changed from a blackish to a blue, if
the former, or a red colour if the latter salt has been used. A more
absolutely conclusive proof is to lay a piece of filter paper soaked in
dilute hydrochloric acid upon the stain, and then to test for iron upon
the paper with ferrocyanide or thiocyanate. The freedom of the paper
itself from iron must be ascertained before use. Iron-stains produced in
the salted state are more difficult to discharge than those which are
caused later in the tanning process, since iron salts have distinct
tanning power, and attach themselves firmly to the untanned fibre. On
the Continent, where common salt is heavily taxed, alum, carbolic acid,
naphthalene and other materials are frequently added to it to
“denaturise,” or render it incapable of being used as food, and these
additions are often the cause of trouble to the tanner.
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