The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
The gas is most conveniently produced by burning sulphur, which produces
double its weight of sulphur dioxide. If used for “stoving” drying rooms
and other places infested with moulds, care must be taken to avoid risk
of fire. A shallow cast-iron pot set on bricks or sand is generally the
most suitable vessel, and the sulphur may be ignited by a piece of
red-hot iron or a rag which has been previously dipped in melted
sulphur. It is corrosive to metalwork, and bleaches many colours, but
does not produce any marked injurious effect on leather, though the
sulphuric acid formed by oxidation may, if not removed, ultimately make
it tender.
For many purposes a solution of the gas is required, and this is most
easily made by burning the sulphur in a small metal or firebrick stove
from which the fumes are sucked through a “scrubber,” which, on a small
scale, is conveniently made of large glazed sanitary pipes, packed with
coke or broken earthenware, over which water is allowed to trickle. The
lowest pipe has an opening for a branch pipe, which is connected with
the stove and rests on three bricks in a tub, which collects the acid
solution and forms a water-seal to prevent the escape of gas. Above the
inlet for the gases is fixed a wooden grating on which the coke rests.
The scrubber may be 10-15 feet in height and connected at the top with a
chimney or steam ejector to produce the draught. The arrangement is
illustrated in Fig. 5. Another method is to burn the sulphur in a closed
cylinder and to force the products through water with an air-compressor
or steam-jet injector.
In place of using a scrubber, the fumes may be blown by a steam ejector
direct into a tank. This is a very good arrangement for washing and
bleaching hair, etc., but where large quantities of solution are
required is inferior to the scrubber. Ejectors of hard lead or regulus
metal should be used, and are less acted on by the dry gases than by the
very dilute moist exhaust from the scrubber (see p. 335).
[Illustration: FIG. 5--Sulphurous acid apparatus.]
_Bisulphites_ have also strong antiseptic properties. “Bisulphite of
soda” (hydric sodic sulphite) solution may be made by supplying the
scrubber with solution of soda-ash or washing soda; bisulphite of lime,
by using milk of lime or packing the scrubber with chalk or limestone
(free from much iron) in place of the coke. In either case a much
stronger solution is obtained than with water alone.
Boakes’ “metabisulphite of soda”[8] is a very convenient source of
sulphurous acid when the latter is wanted in small quantities. It is an
anhydrosulphite, Na₂O.2(SO₂), and contains 67·4 per cent. of its weight
of SO₂. One molecule of the salt (= 190) requires one molecule of H₂SO₄
(= 98) to set free the whole of the sulphurous acid. For many purposes
the sulphate of soda formed may be neglected and the acidified solution
used direct.
[8] Patented by Boakes, Ltd., Stratford, London, E.
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