The Principles of Leather Manufacture — John Shaqi
The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
_Eudermin_ is a tar-oil manufactured by Speyer and Grund, of
Frankfort-on-Main, which is intended as an antiseptic addition to
stuffing greases to prevent mould and spueing. It is recommended for the
purpose by Eitner[10] and can be used in proportions such as 10 per
cent. of the grease. Creasotes and cresols can be dissolved in oils and
stuffing greases, and act as antiseptics, though less powerfully than
in aqueous solution. Rosin oils and turpentine have also antiseptic
properties.
[10] Ibid., 1893, p. 41.
_Creasote_, “heavy coal oil,” or “dead oil,” is a complex mixture of
hydrocarbons, phenols and cresols, obtained by distillation of coal tar,
heavier than water, and almost insoluble in it. It is largely used as a
preservative for timber. Carbolineum is an oil of this class, boiling at
over 300° C., and intended for application to wood. One or more coats
are applied to the dry wood at a temperature of 80° C. The workman’s
hands must be protected by gloves, as the hot creasote raises painful
blisters. Eitner[11] recommends its use for preserving pits, posts and
other woodwork in tanneries. Wood-creasote is a somewhat similar product
obtained from wood-tar.
[11] Gerber, 1889, p. 183.
The heavier cresols are so little soluble in water as to be valueless in
their ordinary form as antiseptics, but several preparations are made
under the names of “Creolin,” “Jeye’s fluid,” “Lysol,” “Izal,” “Soluble
phenyl,” etc., in which they are treated with additions of soap or
alkalies, which cause them to emulsify or dissolve in water, generally
as milky liquids. These are powerful germicides and have the advantage
over phenol of being non-poisonous. 0·1 to 0·5 per cent. solution of
creolin will sterilise hides after bating so that no putrefaction takes
place in the liquors. Mr. J. T. Wood specially recommends creolin for
the general purposes of the tannery, disinfecting pits and tubs, and for
checking the action of puers and drenches on goods which have gone a
little too far, by throwing them into a 0·2 per cent. solution.
_Salicylic acid_, orthohydroxybenzoic acid, C₆H₄OH(COOH), is now
artificially prepared from phenol. It is much less poisonous than the
latter and has no smell, which makes it valuable for certain purposes,
but is too dear for most technical applications. Many bacteria appear to
become gradually habituated to its action, and the same is true of
phenol to a less degree.
Salicylic acid is closely related to protocatechuic and gallic acids,
and, like these, gives a blackish colour with iron salts. It is freely
soluble in hot water, but very sparingly in cold. The addition of 1-2¹⁄₂
parts of sodium phosphate, sulphate, or potassium nitrate to each part
of salicylic acid greatly increases its solubility. It seems much more
powerful in preventing the development of bacteria than carbolic acid;
a solution of 1 part of salicylic acid in 666 of water is said to be
equal in this respect to 1 part of carbolic in 200.
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