The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
_Benzoic acid_, C₆H₅COOH, though not much employed, except in medicine,
is a still more powerful disinfectant, and has the advantage of being
non-poisonous to human beings.
“_Cresotinic acid_,” which is derived from the cresols as salicylic acid
is derived from phenol, is more soluble than salicylic acid. It is not
very poisonous, and a powerful disinfectant. In a crude form it has been
introduced by Hauff, of Feuerbach, for bating or removing lime from
hides. This it does very well, though without the softening action of a
true bate. It has a tendency to produce a pinkish stain, and in some
degree a sort of tanning of the fibre. Its price, moreover, is rather
high for extensive technical use. (See also p. 162.)
“_Anticalcium_” is a more recent preparation introduced as a bate by the
same firm.[12] It is a solution of mixed sulphonic acids derived from
cresols, and has considerable disinfectant powers. It removes lime very
effectively, but from its acid character somewhat swells the skin. It is
used very successfully as a drench for thin skins (p. 163).
[12] Gerber, 1895, p. 133.
“C.T.” (coal-tar) bate is a grey crystalline pasty mass, with a tarry
smell, and is chemically very similar to anticalcium if not identical
with it.
_Naphthalene sulphonic acid_ has strong antiseptic properties. Its use
in bating has been patented by Burns and Cross. (See p. 163.)
_Naphthols_, C₁₀H₇(OH).--These bodies, which have the same relation to
naphthalene as the phenols to benzene, are powerful antiseptics; and
naphthalene itself appears to have antiseptic power, and is occasionally
used for denaturising salt. There are two naphthols, varying in the
position of the OH group in the molecule, and denominated α and β, of
which α naphthol is the more powerful antiseptic and the less poisonous,
though β, being cheaper, is the common commercial article. It is said
that quantities so small as 0·1-0·4 grams of α naphthol per liter are
sufficient to prevent the development of microbes, while of β naphthol
about ten times that quantity is required.
Naphthols are not very expensive, but their value is diminished by the
fact that they are insoluble in water. They are soluble in alkaline
solutions, but their compounds with bases are of much lower antiseptic
value, and the same is true of their alcoholic solutions; when an
alcoholic solution is added to water the naphthol is precipitated, but
if an addition of soap or camphor be made to the alcoholic solution, the
naphthol remains in a very finely divided condition, if not dissolved.
Adopting Eitner’s suggestion with regard to oxynaphthoic acid (see
below), hides may no doubt be sterilised by treatment first with an
alkaline naphthol solution, and then with a very dilute acid to set the
naphthol free.
“_Hydronaphthol_,” β tetra-hydro-naphthol, C₁₀H₁₂O, is obtained by the
reduction of β naphthol by sodium (Rideal). It seems to be an excellent
disinfectant.
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