The Progress of Invention in the Nineteenth Century.Byrn, Edward W. (Edward Wright)
History
The Progress of Invention in the Nineteenth Century.
Byrn, Edward W. (Edward Wright)
Inventions -- History; Inventions -- History -- 19th century
The applications of chemistry in the commercial world have been in
recent years so numerous and varied that it is not possible to do more
than to refer to its uses in the manufacture of soda and potash, of
alcohol, ether, chloroform, and ammonia, in soap making, washing
compounds and tanning, the production of gelatine, the refining of
cotton seed and other oils, the art of oxidizing oils for the
manufacture of linoleum and oil cloth, the manufacture of fertilizers,
white lead and other paints, the preparation of proprietary medicines,
of soda water and photographic chemicals, the manufacture of salt and
preserving compounds, in the fermentation of liquors and brewing of
beer, the preparation of cements and street pavements, the manufacture
of gas, and the embalming of the dead.
The most interesting and, in many respects, the most important,
development of the last twenty-five years has been in
_electro-chemistry_. Electro-chemical methods are now employed for the
production of a large number of elements, such as the alkali and
alkaline earth metals, copper, zinc, aluminum, chromium, manganese, the
halogens, phosphorus, hydrogen, oxygen, and ozone; various chemicals,
including the mineral acids, hydrates, chlorates, hypochlorites,
chromates, permanganates, disinfectants, alkaloids, coal tar dyes, and
various carbon compounds; white lead and other pigments; varnish; in
bleaching, dyeing, tanning; in extracting grease from wool; in
purifying water, sewerage, sugar solutions, and alcoholic beverages. The
present low price of _aluminum_, reduced from $12 per pound in 1878 to
33 cents now, is due to its production by electrical methods. Among the
earliest successful processes is that described in patents to Cowles and
Cowles, No. 319,795, June 9, 1885, and No. 324,658, August 18, 1885, in
which a mixture of alumina, carbon and copper is heated to incandescence
by the passage of a current, the reduced aluminum alloying with the
copper. This has now been superseded by the Hall process (Pat. No.
400,766, April 2, 1889), in which alumina, dissolved in fused cryolite,
is electrolytically decomposed. Practically all the copper now produced,
except that from Lake Superior, is refined electrolytically by
substantially the method of Farmer’s patent (Pat. No. 322,170, July 14,
1885). All metallic sodium and potassium are now obtained by
electrolysis of fused hydroxides or chlorides (Pats. No. 452,030, May
12, 1891, to Castner, and No. 541,465, June 25, 1895, to Vautin). The
production of caustic soda, sodium carbonate, and chlorine by the
electrolysis of brine, is carried on upon a large scale, and will
probably supersede all other methods. Nolf’s process (Pat. No. 271,906,
Feb. 6, 1883), and Caster’s (No. 528,322, Oct. 30, 1894), employ a
receiving body or cathode of mercury, alternately brought in contact
with the brine undergoing decomposition, and with water to oxidize the
contained sodium. _Carborundum_, or silicide of carbon, is largely
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