History, Modern -- 19th century; Nineteenth century
The ignorance of the material nature of gases and of their weight
lies at the bottom of the “Phlogistic Theory,” a theory devised by
Stahl about the year 1690, to account for the phenomena of combustion
and respiration and the recovery or “reduction” of metals from their
“earths” by heating with charcoal or allied bodies. According to
this inverted theory, a substance capable of burning was imagined
to contain more or less phlogiston, a principle which it parted
with on burning, leaving an earth deprived of phlogiston, or
“dephlogisticated,” behind if a metal. This earth, when heated with
substances rich in phlogiston, such as coal, wood, flour, and similar
bodies, recovered the phlogiston, which it had lost on burning, and,
with the added phlogiston, its metallic character. Other substances,
such as phosphorus and sulphur, gave solids or acid liquids, to
which phlogiston was not so easy to add; but even they could be
rephlogisticated. On this hypothesis, it was the earths, and such acid
liquids as sulphuric or phosphoric acids, which were the elements; the
metals and sulphur and phosphorus were their compounds with phlogiston.
The discovery of oxygen by Priestley and by Scheele in 1774, and
the explanation of its functions by Lavoisier during the following
ten years, gave their true meaning to these phenomena. It was then
recognized that combustion was union with oxygen; that an “earth” or
“calx” was to be regarded as the compound of a metal with oxygen; that
when a metal becomes tarnished, and converted into such an earthy
powder, it is being oxidized; that this oxide, on ignition with
charcoal or carbon, or with compounds such as coal, flour, or wood,
of which carbon is a constituent, gives up its oxygen to the carbon,
forming an oxide of carbon, carbonic oxide on the one hand, or carbonic
“acid” on the other, while the metal is reproduced in its “reguline”
or metallic condition, and that the true elements are metals, carbon,
sulphur, phosphorus, and similar bodies, and not the products of their
oxidation.
Public-domain text, read in full here on John Shaqi.
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