History, Modern -- 19th century; Nineteenth century
The discovery that air is in the main a mixture of nitrogen, an inert
gas, and oxygen, an active one, together with a small proportion of
carbonic “acid” (or, as it is now termed, anhydride)—a discovery
perfected by Rutherford, Black, and Cavendish—and that water is a
compound with oxygen of hydrogen, previously known as inflammable air,
by Cavendish and by Watt, finally overthrew the theory of phlogiston;
but at the beginning of this century it still lingered on, and was
defended by Priestley until his death in 1804. Such, in brief, was
the condition of chemical thought in the year 1800. Scheele had died
in 1786, at the early age of forty-four; Lavoisier was one of the
victims of the French Revolution, having been guillotined in 1794;
Cavendish had ceased to work at chemical problems, and was devoting his
extraordinary abilities to physical problems of the highest importance,
while living the life of an eccentric recluse, and Priestley, driven
by religious persecution from England to the more tolerant shores of
America, was enjoying a peaceful old age, enlivened by occasional
incursions into the region of sectarian controversy.
The first striking discovery of our century was that of the compound
nature of the alkalies and of the alkaline earths. This discovery was
made by Humphry Davy. Born in Cornwall in 1778, he began the study of
chemistry, self-taught, in 1796; and in 1799 he became director of
the “Pneumatic Institution,” an undertaking founded by Dr. Beddoes,
at Bristol, for the purpose of experiments on the curative effects
of gases in general. Here he at once made his mark by the discovery
of the remarkable properties of “laughing gas,” or nitrous oxide. At
the same time he constructed a galvanic battery, and began to perform
experiments with it in attempting to decompose chemical compounds by
its means. In 1801 Davy was appointed professor of chemistry at the
Royal Institution, a society or club which had been founded a few
years previously by Benjamin Thompson, Count Rumford, for the purpose
of instructing and amusing its members with recent discoveries in
chemistry and natural philosophy. In 1807 Davy applied his galvanic
battery to the decomposition of damp caustic potash and soda, using
platinum poles. He was rewarded by seeing globules of metal, resembling
mercury in appearance, at the negative pole; and he subsequently proved
that these globules, when burned, reproduced the alkali from which
they had been derived. They also combined with “oxymuriatic acid,” as
chlorine (discovered by Scheele) was then termed, forming ordinary
salt, if sodium be employed, and the analogous salt, “muriate of
potash,” if the allied metal, potassium, were subjected to combustion.
By using mercury as the negative pole, and passing a current through a
strong solution of the chloride of calcium, strontium, or barium, Davy
succeeded in procuring mixtures with mercury or “amalgams” of their
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