History, Modern -- 19th century; Nineteenth century
Marsh Olefiant | Carbonic Carbonic
Gas Gas | Oxide Acid
Carbon 6 6 | Carbon 5 6
Hydrogen 1 2 | Oxygen 8 16
Thus the first compound, marsh gas, was regarded by Dalton as
composed of an atom of carbon in union with an atom of hydrogen; or,
to reproduce his symbols, as ⊜◉; while the second, olefiant gas, on
this hypothesis, was a compound of two atoms of hydrogen with one of
carbon, or ◉◍◉. Similarly the symbols ◍○, and ○◍○ were given to the two
compounds of carbon with oxygen. So water was assigned the symbol ◉○,
for Dalton imagined it to be a compound of one atom of hydrogen with
one of oxygen. Compounds containing only two atoms were termed by him
“binary”; those containing three, “ternary”; four, “quaternary,” and
so on. The weight of an atom of oxygen was eight times that of an atom
of hydrogen; while that of an atom of carbon was six times as great
as the unit. By assigning symbols to the elements, consisting of the
initial letters of their names, or of the first two letters, formulas
were developed, indicating the composition of the compound, the atomic
weights of the elements being assured. Thus, NaO signified a compound
of an atom of sodium (natrium), weighing twenty-three times as much as
a similar atom of hydrogen, with an atom of oxygen, possessing eight
times the weight of an atom of hydrogen. Therefore, thirty-one pounds
of soda should consist of twenty-three pounds of sodium in combination
with eight pounds of oxygen, for, according to Dalton, each smallest
particle of soda contains an atom of each element, and the proportion
is not changed, however many particles be considered.
It has been pointed out by Judge Stallo, of Philadelphia, in his
_Concepts of Physics_, that such a hypothesis as that of Dalton is
no explanation; that a fact of nature, as, for example, the fact of
simple and multiple proportions, is not _explained_ by being minified.
Allowing the general truth of this statement, it is, nevertheless,
undoubted that chemistry owes much to Dalton’s hypothesis—a lucky
guess at first, it represents one of the fundamental truths of nature,
although its form must be somewhat modified from that in which Dalton
conceived it. Dalton’s work was first expounded by Thomas Thomson,
professor at Glasgow, in his _System of Chemistry_, published in 1805;
and subsequently in Dalton’s own _New System of Chemical Philosophy_,
the three volumes of which were published in 1808, in 1810, and in 1827.
Public-domain text, read in full here on John Shaqi.
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