History, Modern -- 19th century; Nineteenth century
that on the analogy of the chlorides it was a fair deduction that the
fluorides are compounds of an undiscovered element, fluorine, with
metals; and that hydrofluoric acid is the true analogue of hydrochloric
acid. The truth of this forecast has been established of recent years
by Henri Moissan, who isolated gaseous fluorine by subjecting a mixture
of hydrofluoric acid and hydrogen potassium fluoride contained in a
platinum U tube to the action of a powerful electric current. He has
recently found that the tube may be equally well constructed of copper;
and this may soon lead to the industrial application of the process.
The difficulty of isolating fluorine is due to its extraordinary
chemical energy; for there are few substances, elementary or compound,
which resist the action of this pale yellow, suffocating gas. In 1811
iodine, separated by Courtois from the ashes of sea-plants, was shown
by Davy to be an element analogous to chlorine. Gay-Lussac subsequently
investigated it and prepared many of its compounds; and in 1826 the
last of these elements, bromine, was discovered in the mother-liquor
of sea-salt by Balard. The elements of this group have been termed
“halogens,” or “salt producers.”
While Davy was pouring his researches into the astonished ears of
the scientific and dilettante world, John Dalton, a Manchester
school-master, conceived a theory that has proved of the utmost service
to the science of chemistry, and which bids fair to outlast our day. It
had been noticed by Wenzel, by Richter, by Wollaston, and by Cavendish,
towards the end of the last century, that the same compounds contain
the same constituents in the same proportions, or, as the phrase runs,
“possess constant composition.” Wollaston, indeed, had gone one step
farther, and had shown that when the vegetable acid, oxalic acid, is
combined with potash, it forms two compounds, in one of which the acid
is contained in twice as great an amount relatively to the potash as
in the other. The names _monoxalate_ and _binoxalate_ of potash were
applied to these compounds, to indicate the respective proportions of
the ingredients. Dalton conceived the happy idea that by applying the
ancient Greek conception of atoms to such facts the relative weights
of the atoms could be determined. Illustrating his views with the two
compounds of carbon with hydrogen, marsh gas and olefiant gas, and with
the two acids of carbon, carbonic oxide, carbonic “acid,” he regarded
the former as a compound of one atom of carbon and one of hydrogen, and
the second as a compound of one atom of carbon and two of hydrogen, and
similarly for the two oxides of carbon. Knowing the relative weights
in which these elements enter into combination, we can deduce the
relative weights of the atoms. Placing the relative weight of an atom
of hydrogen equal to unity, we have:
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