History, Modern -- 19th century; Nineteenth century
The molecular complexity of gases has thus gradually become
comprehended, and the truth of Avogadro’s law has gained acceptance.
And as a means of picturing the behavior of gaseous molecules, the
“Kinetic Theory of Gases” has been devised by Joule, Clausius, Maxwell,
Thomson (Lord Kelvin), and others. On the assumption that the pressure
of a gas on the walls of the vessel which contains it is due to the
continued impacts of its molecules, and that the temperature of a gas
is represented by the product of the mass of the molecules, or the
square of their velocity, it has been possible to offer a mechanical
explanation of Boyle’s law, that at constant temperature the volume
of a gas diminishes in proportion as the pressure increases; of
Gay-Lussac’s law, that all gases expand equally for equal rise of
temperature, provided pressure is kept constant; the condition being
that equal volumes of gases contain equal numbers of molecules. A
striking support is lent to this chain of reasoning by the facts
discovered by Thomas Graham (1805–1869), professor at University
College, London, and subsequently master of the Royal Mint. Graham
discovered that the rate of diffusion of gases into each other is
inversely as the square roots of their densities. For instance, the
density of hydrogen being taken as unity, that of oxygen is sixteen
times as great; if a vessel containing hydrogen be made to communicate
with one containing oxygen, the hydrogen will pass into the oxygen and
mix with it; and, conversely, the oxygen will pass into the hydrogen
vessel. This is due to the intrinsic motion of the molecule of each
gas. And Graham found, experimentally, that for each volume of oxygen
which enters the hydrogen vessel four volumes of hydrogen will enter
the oxygen vessel. Now, 4 = √16; and as these masses are relatively
1 and 16, and their temperatures are equal, the square of their
velocities are respectively 1 and 16.
The question of the molecular complexity of gases being thus disposed
of, it remains to be considered what are the relative complexity of
liquid molecules. The answer is indicated by a study of the capillary
phenomena of liquids, one method of measuring which is the height of
their ascent in narrow or capillary tubes. We shall not enter here into
detail as to the method and arguments necessary; suffice it to say that
the Hungarian physicist Eötvös was the first to indicate the direction
of research, and that Ramsay and Shields succeeded in proving that the
complexity of the molecules of most liquids is not greater than that
of the gases which they form on being vaporized; and also that certain
liquids, _e.g._, water, the alcohols, and other liquids, are more or
less “associated,” _i.e._, their molecules occur in couplices of two,
three, four, or more, and as the temperature is raised the complexity
of molecular structure diminishes.
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