History, Modern -- 19th century; Nineteenth century
As regards the molecular complexity of solids, nothing definite
is known, and, moreover, there appears to be no method capable of
revealing it.
While the researches of which a short account has now been given have
led to knowledge regarding the nature of molecules, the structure
of the molecule has excited interest since the early years of the
century, and its investigation has led to important results. The
fact of the decomposition of acidified water by an electric current,
discovered by Nicholson and Carlisle, and of salts into “bases” and
“acids” by Berzelius and Hisinger in 1803, led to the belief that
a close connection exists between electric energy, or, as it was
then termed, “electric force,” and the affinity which holds the
constituents of chemical compounds in combination. In 1807 Davy
propounded the theory that all compounds consist of two portions, one
electro-positive and the other electro-negative. This idea was the
result of experiments on the behavior of substances, such, for example,
as copper and sulphur—if portions of these elements be insulated and
then brought into contact they become oppositely electrified. The
degree of electrification is intensified by rise of temperature until,
when combination ensues, the electrification vanishes. Combination,
therefore, according to Davy, is concurrent with the equalization of
potentials. In 1812 Berzelius brought forward an electro-chemical
theory which for the following twenty years was generally accepted.
His primary assumption was that the atoms of elements, or, in certain
cases, groups of atoms, are themselves electrified; that each atom, or
group of atoms, possesses two poles, one positive, the other negative;
that the electrification of one of these poles predominates over
that of the other, so that the atom or group is itself, as a whole,
electro-positive, or electro-negative; that combination ensued between
such oppositely electrified bodies by the neutralization, partial or
complete, of their electric charges; and, lastly, that the polarity
of an element or group could be determined by noting whether the
element or group separated at the positive or at the negative pole of
the galvanic battery, or electrolysis. For Berzelius, oxygen was the
most electro-negative and potassium the most electro-positive of the
elements, the bridge between the “non-metals” and the “metals” being
hydrogen, which, with nitrogen, forms a basic, or electro-positive,
group, while with chlorine, etc., it forms electro-negative groups.
The fact that an electric current splits compounds in solution
into two portions led Berzelius to devise his “dualistic” system,
which involved the assumption that all compounds consist of two
portions, one electro-positive, the other electro-negative.
Thus sulphate of magnesium and potassium was to be regarded as
composed of electro-positive potassium sulphate in combination
with electro-negative magnesium sulphate; the former in its turn
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