History, Modern -- 19th century; Nineteenth century
consisted of electro-negative sulphur trioxide (SO3) in combination
with electro-positive oxide of potassium (K2O); while each of these
proximate constituents of potassium sulphate were themselves composed
of the electro-negative oxygen in combination with electro-positive
sulphur, or potassium. On contrasting sulphur with potassium, however,
the former was considered more electro-negative than the latter; so
that the group SO3 as a whole was electro-negative, while K2O was
electro-positive. The symbols given above, which are still in universal
use, were also devised by Berzelius for the purpose of illustrating and
emphasizing his views. These views, however, met with little acceptance
at the time in England.
Lavoisier’s idea, that oxygen was the necessary constituent of all
acids, began about this time to lose ground. For Davy had proved the
elementary nature of chlorine; and hydrochloric acid, one of the
strongest, was thus seen to contain no oxygen, and Davy expressed the
view, founded on his observation, that iodic “acid,” I2O5, was devoid
of acid properties until dissolved in water, and that the essential
constituent of all acids was hydrogen, not oxygen. The bearing of this
theory on the dualistic theory is, that while, _e.g._, sulphuric acid
was regarded by Berzelius as SO3, containing no hydrogen, and was
supposed to be separated as such at the positive pole of a battery,
Davy’s suggestion led to the opposite conclusion that the formula
of sulphuric acid is H2SO4, and that by the current it is resolved
into H2 and SO4. Faraday’s electrolytic law, that when a current is
passed through electrolytes in solution the elements are liberated in
quantities proportional to their equivalents, led to the abandonment
of the dualistic theory. For when a current is passed in succession
through acidified water, fused lead chloride, and a solution of
potassium sulphate, the quantities of hydrogen and oxygen from the
water, of lead and chlorine from the lead chloride, and the potassium
of the sulphate are in accordance with Faraday’s law. But in addition
to the potassium there is liberated at the same pole an equivalent of
hydrogen. Now, if Berzelius’s theory be true, the products should be
SO3 and K2O, but if the opposite view be correct, then K2 is liberated
first and by its subsequent action on water it yields potash and
its equivalent of hydrogen. This was pointed out first by Daniell,
professor at King’s College, London, and it was regarded as a powerful
argument against Berzelius’s system. In 1833, too, Graham investigated
the phosphoric acids, and prepared the salts of three, to which he
gave the names, _ortho-_, _pyro-_, and _meta-_ phosphoric acids. To
understand the bearing of this on the doctrine of dualism it must be
remembered that P2O5, pentoxide of phosphorus, was at that date named
phosphoric acid. When dissolved in water it reacts with bases, forming
salts—the phosphates. But the quantity of water necessary was not then
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