History, Modern -- 19th century; Nineteenth century
It must be understood that the ions K and NO3 are not, strictly
speaking, atoms; they are _charged_ atoms; the K retains a +, and the
NO3 a − charge. On immersing into the solution the poles of a battery,
one charged + and the other −, the + K atoms are attracted to the −
pole, and are there discharged; as soon as they lose their charge they
are free to act on the water, when they liberate their equivalent of
hydrogen. Similarly, the − NO3 groups are discharged at the + pole, and
abstract hydrogen from the water, liberating an equivalent quantity
of oxygen. Thus the phenomenon of electrolysis, so long a mysterious
process, finds a simple explanation. The course of ordinary chemical
reactions is also readily realized when viewed in the light of this
theory. Take, for example, the ordinary equation:
AgNO3.Aq + NaCl.Ag = AgCl + NaNO3.Aq;
_i.e._, solutions of silver nitrate and sodium chloride give a
precipitate of silver chloride, leaving sodium nitrate in solution. By
the new views, such an equation must be written:
+ − + − + −
Ag.Aq + NO3.Aq + Na.Aq + Cl.Aq = AgCl + Na.Aq + NO3.Aq.
The compound, silver chloride, being insoluble in water, is formed
by the union of the ions Ag and Cl, and their consequent discharge,
forming an electrically neutral compound; while the sodium ions,
charged positively together with the NO3 ions, negatively charged,
remain in solution.
One more application of the principle may be given. Many
observers—Andrews, Favre, and Silbermann, but especially Julius
Thomsen, of Copenhagen, and M. Berthelot, of Paris—have devoted much
labor and time to the measurement of the heat evolved during chemical
reactions. Now, while very different amounts of heat are evolved when
chlorine, bromine, or iodine combine respectively with sodium or
potassium, the number of heat units evolved on neutralizing sodium
or potassium hydroxide with hydrochloric, hydrobromic, hydriodic, or
nitric acids is always about 13,500. How can this fact be explained? It
finds its explanation as follows: These acids and bases are ionized in
solution as shown in the equation:
+ − + − + −
H.Aq + Cl.Aq. + Na.Aq + OH.Aq = H.OH + Na.Aq + Cl.Aq.
Water is the only compound formed; and it is produced by the union
of the hydrogen-ion originally belonging to the acid, and the OH or
hydroxyl-ion originally belonging to the base. No further change has
occurred; hence the uniform evolution of heat by the interaction of
equivalent quantities of these acids and bases.
It now remains to give a short account of the greatest generalization
which has as yet been made in chemistry. It has been termed the
“Periodic Arrangement of the Elements.”
Public-domain text, read in full here on John Shaqi.
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