History, Modern -- 19th century; Nineteenth century
In 1864 Newlands, of London, and Lothar Meyer, late of Tübingen, found
that by arranging the elements in the order of their atomic weights
certain regularities were to be observed between each element, and
in general the eighth in succession from it, in the order of their
numerical value. Such similar elements formed groups or quantities;
while the elements separating them belong to a _period_, hence the name
“periodic arrangement.” Commencing with lithium, a light, lustrous
metal found in silicate in certain minerals, we have the following
series:
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
7 9.2 11 12 14 16 19 20
Sodium Magnesium Aluminum Silicon Phosphorus Sulphur Chlorine Argon
23 24.3 27 28 31 34 35.5 40
and so on. It is unnecessary to point out in detail the resemblances
between the elements which stand in the vertical columns; but it
may be stated that the resemblance extends also to the formulas and
properties of their compounds. Thus the chlorides of lithium and sodium
are each white soluble salts, of the formulas LiCl and NaCl; oxides of
magnesium and of beryllium are both insoluble white earthy powders,
MgO and BeO (GeO), and so on. Newlands, in his preliminary sketch,
termed this order the “Law of Octaves,” and predicted the existence of
certain undiscovered elements which should occupy unfilled positions in
the table. Mendeléef, professor at St. Petersburg, in 1869 amplified
and extended these relations; and he and Meyer pointed out that the
volume occupied by equal numbers of atoms of such elements underwent
a periodic variation when the elements are classified as above.
The prediction of undiscovered elements was made by Mendeléef in a
more assured manner; and in several cases they have been realized.
Thus what Mendeléef called “ekaboron” has since been discovered by
Lecoq de Boisbandron and named, patriotically, “gallium”; Mendeléef’s
“eka-silicon” is now known as “germanium,” discovered by Winkler; and
“eka-aluminum” is now Cléve’s “scandium.” Moreover, the atomic weights
of cæsium, beryllium, molybdenium, and mercury have been altered so
that they fit the periodic table; and further research has justified
the alteration.
The valency of these elements increases from right to left, as will be
seen by inspection of the following series:
LiCl BeCl3 BCl3 CCl4 NH4Cl
Na2O MgO B2O3 SiO2 PCl3
Monad. Dyad. Triad. Tetrad. Triad and Pentad.
OH2 FH Ne——
SO3 Cl(OH)O3 A——
Dyad and Hexad. Monad and Heptad. No valency.
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