History, Modern -- 19th century; Nineteenth century
The elements of no valency are of recent discovery. In 1894 Lord
Rayleigh had determined the density of the nitrogen of the atmosphere,
having separated from it the oxygen and carbon dioxide which is mixed
with nitrogen in air. He found it to be of somewhat higher density
than that obtainable from ammonia and other compounds of nitrogen.
In conjunction with Ramsay he investigated atmospheric nitrogen; it
was absorbed either by a method devised by Cavendish, or by making it
combine with magnesium at a red heat. They found that the unabsorbable
residue possessed an unknown spectrum, and that its density was nearly
20. To this new gas they gave the name “argon,” or inactive, seeing
that all attempts to cause it to enter into combination had failed.
In 1895 Ramsay, searching for possible combinations of argon in
minerals, experimented with one which had been previously examined by
Hillebrand, of Baltimore, and obtained from it helium, a gas of density
2, possessing a spectrum which had been previously discovered in 1868
in the chromosphere of the sun, by Jannsen, of Paris, and named helium
by Frankland and Lockyer. Subsequent liquefaction of crude argon by
means of liquid air, prepared by a process invented simultaneously by
Linde and Hampson, gave a residue which was named by its discoverers,
Ramsay and Travers, “neon.” Liquid argon has yielded two other gases
also, “krypon” and “xenon.” These elements form a separate group in the
Periodic Table, commencing with helium, with atomic weight, 4; neon,
20; argon, 40; krypon, 82; and xenon, 128. They all agree in being
mono-atomic, _i.e._, their molecules consist of single atoms; and they
have no tendency to form compounds, _i.e_., they possess no valency.
Public-domain text, read in full here on John Shaqi.
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