The Puering, Bating & Drenching of Skins — John Shaqi
The Puering, Bating & Drenching of SkinsWood, Joseph Turney
Science
The Puering, Bating & Drenching of Skins
Wood, Joseph Turney
Leather
The effect of washing depends on the character of the water (hard or
soft), and also on its temperature. Hard waters should have a small
quantity of clean lime added to them before entering the goods, in
order to remove dissolved CO_{2}, which, by carbonating the lime on
the surface of the skins, renders the grain harsh and the subsequent
puering difficult.
With regard to temperature, it is preferable to employ cold water
until the bulk of the lime is out, since this dissolves more lime than
warm water. 100 c.c. of saturated lime water, at 10° C., contains
0·134 grm. CaO. 100 c.c. at 40° C. contains 0·1119 grm. CaO. Moreover,
a comparatively small rise of temperature causes a considerable
decomposition in a fully limed skin, by which the skin substance is
rendered more soluble, and consequently lost for the purposes of the
tanner. For a fully limed skin the limit of temperature is about 82° F.
(28° C.), whereas a skin free from lime or alkali may be submitted to
a temperature of 120° F. (49° C.) without damage to the fibre. Lamb
prefers a short washing of half an hour in water at 35° to 38° C., for
the reason that the increased temperature causes the goods to become
more flaccid, but this condition is attained at the expense of the loss
of skin substance we have mentioned.
[Illustration: Fig. 2.--Cubical Truck.]
In order to save time and water, the following method is adopted. The
goods are measured by means of a cubical truck on wheels (Fig. 2); it
holds 250 kilos of wet skins (550 lb.). Four of such trucks are placed
in a wash wheel, and a stream of water from a 1-in. pipe turned on. The
goods are run from three-quarters of an hour to one hour; the water is
then stopped, and 4000 c.c. of commercial hydrochloric acid (18° Bé.)
is run in slowly, in a very diluted state, through a perforated lead
pipe. After all the acid has run in, the wheel is run for half an hour,
then water turned on again for half an hour in order to wash away
the calcium chloride produced. During this last washing, hot water is
admitted at the back of the wheel through a perforated pipe, in order
to raise the temperature of the goods, so that they do not enter the
puer wheel in a cold condition, and thus lower the temperature of the
puer liquor. The goods are now ready for puering.
The chemical action of the acid is a very simple one, and is expressed
by the formula--
Ca(OH)_{2} + 2HCl = CaCl_{2} + 2H_{2}O
74 + 73·1 = 110·9 + 36[7]
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