The Rare Earths: Their Occurrence, Chemistry, and Technology — John Shaqi
The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Tetragonal; habit octahedral.
G = 3·82-3·95. H = 5¹⁄₂-6. Transparent to opaque; brown to black.
Dauphiné; Bavaria; Cornwall; Norway; Brazil, etc.
_Ancylite._
4Ce(OH)CO₃ + 3SrCO₃ + 3H₂O; with Fe, Mn, Ca, F, traces. Cer = 46·3%.
Rhombic; prismatic.
G = 3·95. H = 4¹⁄₂. Brown; translucent.
Plain of Narsarsuk, Greenland.
_Annerödite._
A parallel growth of Columbite on Samarskite, once believed to be a
new species.
Corresponding to Columbite.
Arfvedsonite.
Metasilicate of Na, Ca, Fe´´, Zr; approximately
4Na₂O,3CaO,14FeO,(Al,Fe)₂O₃,21SiO₂. ZrO₂ = 1-6%.
Monoclinic--an amphibole.
G = 3·44. H = 6. Black; pleochroism strong.
S. Greenland and S. Norway.
Arizonite.
Ferric metatitanate, Fe₂O₃,3TiO₂ or Fe₂(TiO₃)₃. TiO₂ = 36·7%.
Uncertain; apparently monoclinic.
G = 4·25. H = 6-7. Dark steel-grey; opaque.
Hackberry, Arizona.
_Arrhenite._
Silico-tantalate of Yttrium metals, with Ce, Al, Fe, Ca, Be, aq. Yttr
= 33·2; Cer = 2·6; ZrO₂ = 3·4%.
Amorphous.
G = 3·68. Red; translucent to opaque.
Ytterby, Sweden.
Astrophyllite.
Titano-silicate of Fe, Al, Mn, Zr, K, Na, with aq. ZrO₂ = 1·2-4·5;
TiO₂ = 7-14%.
Rhombic. Cleavage (010) perfect.
G = 3·2-3·4. H = 3. Golden to bronze yellow; strongly pleochroic.
Brevik, Norway; El Caso Co., Colorado; Greenland.
_Auerbachite._
An impure hydrated form of Zircon, ZrSiO₄. ZrO₂ = 55·2%.
Tetragonal; isotropic. Pseudomorphous after zircon.
G = 4·06. H = 6. Brownish-grey; translucent to opaque.
Alexandrovsk, Russia.
_Auerlite._
3ThO₂,[3SiO₂,P₂O₅]6H₂O; traces of Fe, Ca, Mg, Al, CO₂, etc. SiO₂
replaced by P₂O₅/3? ThO₂ = 69·2-72·2%.
Tetragonal; probably a pseudomorph after Thorite.
G = 4·4-4·8. H = 2-3. Yellowish to orange-red.
Henderson Co., N. Carolina.
~Baddeleyite.~
ZrO₂, with small amounts of SiO₂, Fe₂O₃, Al₂O₃, CaO, etc. ZrO₂ =
96·5%.
Monoclinic.
G = 4·4-6·0. H = 6¹⁄₂. Brown; pleochroic.
São Paulo, Brazil; Rakwana, Ceylon.
_Bagrationite._
A variety of Allanite (orthite) with no important chemical difference.
Monoclinic; habit prismatic.
G = 3·84. H = 6¹⁄₂. Black; translucent to opaque.
Achmatovsk, Urals.
_Bastnäsite_ (Harmatite).
Hydrated fluocarbonate of Cerium metals, E(F)CO₃. Cer = 64-93·5; ThO₂
= 0-10%.
Hexagonal prisms, pseudomorphous after Tysonite (_q.v._); or massive.
G = 4·9-5·2. H = 4-4¹⁄₂. Yellow to brown; transparent.
Bastnäs, Sweden; Pike’s Peak, Colorado.
~Beckelite.~
Zirconosilicate of rare earths and lime, Ca₃E₄(Si,Zr)₃O₁₅. Cer = 59·7;
Yttr = 2·8; ZrO₂ = 2·5%.
Cubic, in octahedra and dodecahedra. Cubic cleavage.
G = 4·15. Brown; transparent.
Near Sea of Azov, Russia.
Benitoite.
A Titano-silicate of barium, BaTiSi₃O₉. TiO₂ = 20·1%.
Rhombohedral.
H = 6¹⁄₂-7. Colourless to blue; transparent; pleochroism strong.
Source of San Benito River, California.
~Blomstrandine.~
Public-domain text, read in full here on John Shaqi.
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