The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
[488] Water-gas is a mixture of equal volumes of carbon monoxide and
hydrogen, obtained by blowing steam through a glowing coke furnace. At
intervals the steam is shut off, and air is blown through to raise the
temperature of the coke.
In the year previous to that in which Faraday first carburised
water-gas, Berzelius had observed that thoria and zirconia, when heated
in a non-luminous flame, emit an intense white light. Similar behaviour
had long before been observed in the cases of magnesia, alumina, lime,
zinc oxide, etc. The first practical application of this property of the
oxides was that of Drummond, who in 1826 heated a pencil of lime in the
oxy-hydrogen flame and obtained the intense white light which has since
become so familiar as the Drummond or ‘lime-light.’ A further
development in this direction was due to du Motay and Maréchal, who in
1867 illuminated the Place de Tuileries and the Hôtel de Ville in Paris
by means of pencils of compressed zirconia--magnesia was also
used--heated by means of oil vapour and oxygen.
The use of non-luminous flames to secure illumination, by raising the
temperature of solids suspended in them to the point of incandescence
was proposed in 1839 by Cruickshank, who used a mantle of platinum wire,
covered with lime and rare earths, which he heated by means of
water-gas. In 1846 Gillard employed mantles of platinum wire, raised to
incandescence in the flame of burning hydrogen, which he obtained by
passing steam over heated iron wire; later he used water-gas (1848), his
lamps with this modification being employed in Paris and in
Philadelphia. Narbonne was later illuminated (1856-1865) by a similar
device, but permanent success could hardly be obtained in view of the
cost of the platinum mantles, which lasted only a few months. The same
mantle was proposed in 1882 by Lewis, the ordinary Bunsen flame being
suggested as the source of heat. In the same year Popp exhibited at the
Crystal Palace lamps in which a platinum mantle was raised to
incandescence by means of a flame of coal-gas and heated air. These
attempts, however, served only to show that no permanent advance could
be made in this direction.
Public-domain text, read in full here on John Shaqi.
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