The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Crystals, orthorhombic, holosymmetric; _a_ : _b_ : _c_ = 0·9988 : 1 :
0·8127. Usual forms--the Pinakoids _a_, _b_, and _c_ {100}, {010} and
{001}, prisms _m_ {110} and _q_ {130}, domes _u_ {101}, _t_ {301} and
_n_ {011}, and some pyramids {hkl}.
Angles, _a_ ∧ _m_ = 44° 58´, _u_ ∧ _c_ = 39° 8´, _n_ ∧ _c_ = 39° 6´.
The crystals usually occur as short prisms. No cleavage. Optical
constants unknown. In flakes the absorption spectrum of didymium can
be observed.
The mineral is brittle; hardness 5 to 6 on Mohs’ scale; sp. gr. varies
a little about 4·9. Fracture splintery; lustre dull, resinous. Colour
brown to red and greyish-red, streak greyish-white. The mineral is
almost opaque.
Cerite is infusible before the blowpipe. It is attacked readily by
sulphuric acid, less easily by hydrochloric acid, with which it gives a
gelatinous mass. Rammelsberg[16] found that the silica left behind on
treatment of the powdered granular variety with the latter acid
contained a variable proportion of bases, which he obtained and
estimated after fusing the siliceous residue with sodium carbonate. From
the different proportions of the earths in the part attacked by the acid
and that left in the silica, he remarks, ‘It would almost appear that
Cerite is a mixture of silicates which are not all attacked with the
same ease by hydrochloric acid.’ Apparently without previous knowledge
of this observation, Welsbach[17] noticed the same thing in 1884. He
concluded that ordinary granular ‘cerite’ is a mixture of several
minerals, among which there are at least two which contain rare earths.
Of these, one, the chief constituent of the aggregate, is probably
identical with the crystallised mineral, and is characterised by the
readiness and completeness with which it is attacked by hydrochloric
acid. The other does not react, with hydrochloric, but is readily
attacked by sulphuric acid; it contains yttria earths, in addition to
the ceria earths. In the extraction of ceria earths from the mineral
aggregate, Welsbach used hydrochloric acid, so leaving this second
mineral unchanged; but to avoid loss of the rare earths, sulphuric acid
is more commonly employed for the decomposition.
[16] _Pogg. Ann._, 1859, ~107~, 631.
[17] _Monats._, 1884, ~5~, 512.
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