The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Though of great historical interest, cerite is of very small importance
for the extraction of rare earths at the present time, on account of its
very rare occurrence. The mineral seems to be almost entirely confined
to the Bastnäs quarry near Ryddarhyttan, Sweden, where it is found with
the rare earth silicate allanite (_q.v._), biotite, hornblende, bismuth
glance, chalcopyrite, etc. Here it was observed in 1751 by Cronstedt,
who called it Tungsten (_vide supra_, p. 1). In 1781 Scheele examined a
specimen of Wallerius’s ‘Tenn-spat’ from Bipsberg, Dalecarlia, and found
Tungstic Oxide (Acid), WO₃, in it.[18] After Scheele’s work, the
Ryddarhyttan mineral was known as Red Tungsten, until Bergmann (1780)
and d’Elhuyar (1784) showed that the two minerals were chemically
distinct. They considered the red variety to be a silicate of iron and
calcium, the rare earths being mistaken for lime. In 1804 Klaproth
examined it, and found a new earth; he called the mineral ‘Ochroite,’
from its colour. In the same year, but independently of Klaproth,
Berzelius and Hisinger made the same discovery; they called the mineral
Cerite and the new metal Cerium, in honour of the discovery of the minor
planet Ceres by Piazzi in 1801.
[18] This mineral, which Scheele knew as Tungstein, is now called
Scheelite.
The analyses of cerite made in the earlier part of the nineteenth
century resulted in some confusion. Klaproth in 1807 found 34·5 per
cent. SiO₂ in a specimen (his Ochroite); Vauquelin in 1805, and Hisinger
in 1810, found 17·0 and 18·0 per cent. respectively.[19] Hermann[20]
called attention to this discrepancy in 1843 (and again in 1861), and
declared that the two could not be the same. For Klaproth’s mineral he
proposed to revive the name Ochroite, whilst from his own analyses he
proposed for the cerite of Berzelius the name Lanthanocerite, having
found carbon dioxide and lanthanum, with much less cerium, in the
latter.[21] In 1861 Kenngott partly explained these results by showing
that the sample of cerite which Hermann had analysed contained
Lanthanite[22]; but the extraordinarily high percentage of silica
obtained by Klaproth remained unexplained. It may have been due to
impurities of high silica content in the specimen he examined.
[19] _Vide_ Hintze, _Handbuch der Mineralogie_, Leipzig, 1897, ~ii.~,
1329.
[20] Hermann, _J. pr. Chem._ 1843, ~30~, 194, and 1861, ~82~, 406.
[21] The announcement of the discovery of Lanthanum by Mosander was
made in 1839.
[22] Lanthanite (see list) is an hydrated carbonate, R₂O₃,3CO₂,9H₂O,
where R = cerium metals, chiefly Lanthanum.
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