The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Crystals commonly prismatic, terminated by _c_. Faces rough and
coarse; lustre vitreous to greasy, seen only on freshly-broken
surfaces. Brittle. No cleavage. Fracture conchoidal to splintery.
Hardness 6¹⁄₂-7; sp. gr. 4·0-4·5.
Colour black, greenish- and brownish-black; green and transparent in
flakes. The crystalline variety has strong positive birefringence,
with the plane of the optic axes parallel to (_b_), the plane of
symmetry; the amorphous variety is of course isotropic. The brown
variety shows very distinct pleochroism, _i.e._ the colour as seen by
transmitted light varies with the direction in which the light
traverses the crystal; the green kinds have much weaker pleochroism.
Gadolinite is of common occurrence in the pegmatite veins of the
Scandinavian granite. It was first found in a felspar quarry on the
island of Ytterby, near Stockholm, by a Lieutenant Arrhenius[24]; it is
also found, together with a large number of other rare earth minerals,
at Fahlun. It occurs in Norway on the islands of Hitterö and Malö, and
in Germany in the Riesengebirge and the Harz. Probably the largest
deposit is that in Texas, at Barringer Hill, near Bluffton, on the west
bank of the Colorado River, Llano County, now owned and worked by the
Nernst Light Company of Pittsburg; in 1904 a mass of very pure
gadolinite weighing 200 lb. was found here.[25]
[24] _Vide_ Geijer, _Crell’s Chemische Annalen_, 1788, ~1~, 229.
[25] See _U.S. Geol. Survey_ (_Minerals_), 1904, 1213.
In the same place a decomposition product of gadolinite was discovered
by Hidden and Mackintosh in 1889. They named it Yttrialite or Green
Gadolinite. It contains no beryllium, and twice as much silica as the
parent mineral, and approximates to the formula R₂O₃,2SiO₂, where R₂O₃
is chiefly yttria oxides; it is thus similar in composition to the newly
found scandium silicate, Thortveitite (_q.v._). It is amorphous and
massive; and is often found in continuous growth with gadolinite. Pieces
up to 10 lb. in weight have been obtained.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account