The Rare Earths: Their Occurrence, Chemistry, and Technology — John Shaqi
The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
As stated above, Gadolinite was discovered by Arrhenius in 1788. Geijer
examined it in the same year, and described it as a black zeolite. In
1794 it was analysed by Gadolin, who declared it to be a silicate of
iron, aluminium, and a new element which he called Ytterbium. In 1797
Ekeberg examined it, and confirmed the discovery. He proposed the name
Gadolinite for the mineral, and Yttria for the new earth; these names
were accepted by Klaproth, who examined it with Vauquelin in 1800, and
by the French crystallographer Haüy. In 1802 Ekeberg showed that the
oxide originally taken for alumina was in reality beryllia; in 1816
Berzelius showed that ceria was present with the yttria.[26] About 1838
Mosander began his classical work on the earths in gadolinite. In that
year he announced the separation of Lanthana,[27] and in 1842 that of
Didymia, which he had actually discovered eighteen months earlier. In
the latter year he announced[28] the separation of erbia and terbia. In
1842 also Scheerer[29] declared that the yttria from gadolinite was a
mixture of earths, from its different behaviour on heating in closed and
open vessels; but when Mosander announced the discovery of didymia (the
announcement appears to have been hastened indeed by Scheerer’s
observation) it was agreed that the colouration observed was probably
due to that earth. The further history of these earths must be continued
elsewhere (_vide_ p. 111).
[26] _Schweigg. J._, 1816, ~16~, 405.
[27] Berzelius (a letter to Pelouze), _Pogg. Ann._, 1839, ~46~, 648.
[28] _Berz. Jahres._, ~23~, 145; ~24~, 105.
[29] _Pogg. Ann._, 1842, ~56~, 483.
The behaviour of gadolinite on heating is of great interest. When heated
uniformly, in closed or open vessels, the mineral suddenly glows very
strongly at a definite temperature (according to Hofmann and Zerban[30]
at 430°C.), with considerable alteration in properties. The amorphous
variety exhibits the phenomenon much more markedly than the crystalline
form. The change in the two cases is entirely distinct, the only effect
in common being that both varieties are rendered insoluble in acids
after the glowing. The amorphous variety, in the act of glowing, changes
to the crystalline form.
[30] _Ber._, 1903, ~36~, 3095.
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