The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Now it can be shown that the volumes of equal numbers of molecules in
the arrangements A and B will be to one another as the height, H, of an
equilateral triangle, to the height, h, of a regular tetrahedron whose
edges are equal to the sides of the triangle, a length R (which will be
equal to the diameter of a molecule).
Then H = ¹⁄₂R√3, _h_ = R√²⁄₃.
Then vol. in arrangement A : vol. in arr. B ∷ H : _h_
_i.e._ ∷ √3/2 : √²⁄₃
∷ 1 : 0·943.
That is, the volume changes in the ratio 1 to 0·943, the amorphous
variety of gadolinite consisting of molecules in arrangement A, which go
over to the closer packed arrangement B in the change to the crystalline
form.
More extended work has shown that this ingenious and interesting
explanation is not of general application. Thus H. Rose[33] found that
samarskite (_q.v._) exhibited the phenomenon of glowing, but that the
specific gravity was actually less after the change than it was before,
_i.e._ there was an increase of volume. Damour observed glowing in the
case of zircon from Ceylon (_q.v._) with increase of density, the volume
change being from 1 to 0·922, _i.e._ even greater than for gadolinite.
Again, Hauser[34] observed in the case of his new rare earth mineral
risörite a sudden change at a red heat, the mineral losing water,
becoming very brittle, and increasing very considerably in specific
gravity (the volume changing from 1 to 0·90 approximately), but without
glowing. Ramsay and Travers[35] found that fergusonite (_q.v._) glowed
strongly when heated to 500°-600°, with decrease of specific gravity
(5·62 before to 5·37 after), evolution of all its helium, and very
considerable evolution of heat; they suggested that helium was present
in combination, in an endothermic compound decomposed by heat, but in
view of the properties of helium, this hypothesis seems hardly tenable.
[33] _J. pr. Chem._ 1858, ~73~, 391.
[34] _Ber._ 1907, ~40~, 3118.
[35] _Zeitsch. physikal. Chem._ 1898, ~25~, 568.
Public-domain text, read in full here on John Shaqi.
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