This phenomenon of phosphorescence, or glowing, on heating, with a change in properties, was first observed by Berzelius in 1816. He found that the oxides of many metals, _e.g._ chromium, tantalum, and rhodium, became denser and insoluble in acids after being heated. Later in the same year he observed the glowing, with a similar change in properties, in the case of a gadolinite from Fahlun.[31] Apparently without knowledge of this observation, Wollaston published a similar account of the glowing of a gadolinite in 1825. In 1840 Scheerer noted an almost identical change in the case of the mineral allanite (_q.v._). Scheerer made a careful study of the phenomena in the cases of allanite and gadolinite.[32] In each case he found that the variety of lower specific gravity showed, on heating, a very strong phosphorescence, accompanied by change of colour and optical properties, and a marked increase of specific gravity. Gadolinite suffered no appreciable loss of weight, but allanite had lost a little water after the change. Careful measurement of the specific gravity before and after the change showed, in the case of two varieties of gadolinite and one of allanite, that the volume had decreased in the ratio 1 : 0·94. Scheerer assumed that this ratio was constant for all such cases, and advanced a general explanation. We know now that numerous cases of similar phenomena occur, in which the change of volume is quite different; but Scheerer’s explanation is so ingenious, and so foreshadows some modern theories, that it is given here in full. [31] _Schweigg. J._, 1816, ~16~, 405. [32] _Pogg. Ann._, 1840, ~51~, 493. He ascribes the alteration to ‘interatomic change, involving change of relative position of atoms and decrease of interatomic distances.’ (Scheerer and the chemists of that period understood by atoms the ultimate particles of a body, making no distinction between elements and compounds; in this case he meant by atoms what we mean by molecules, and the word ‘molecule’ has therefore been substituted for ‘atom’ in what follows.) The change is simply one of closer packing of the molecules, which take up a more stable position with liberation of energy as heat and light. He imagines his molecules as uniform spheres arranged in horizontal layers, as shown in Fig. 1. In placing one layer vertically over another there are three possible arrangements, of which only two concern us. In the arrangement for closest packing, B, say, a molecule of any one layer touches three molecules in each of the layers above and below, which with the six it touches in its own layer make twelve altogether. In the next closest arrangement, A, say, a molecule of any one layer touches only two molecules in each of the layers above and below it, so that one molecule is in contact with ten others altogether. [Illustration: FIG. 1]